Lecture Exam 3 Flashcards
diffusion (definition)
movement of molecules across a selective (semi-permeable) barrier from high concentration to low concentration
selective (semi-permeable) barrier (definition and example)
barrier that allows water molecules to pass thru, but not most of the molecules dissolved in the water
ex. plasma membrane
osmosis (definition)
diffusion of water molecules across a selective (semi-permeable) barrier from high concentration to low concentration
solutes
molecules that are dissolved in water
concentration of water is determined by:
concentration of solutes in the water
solute potential (psi s) (definition)
measure of the concentration of solutes dissolved in water
pure water has ___ solutes
psi s = ___
no solutes
psi s = 0
psi s = 0 (value and what it means for water)
highest value
water molecules are most concentrated
adding solutes ____ psi s
lowers
psi s < 0 (negative value)
as solute concentration increases, psi s ____ and water concentration _____
psi s decreases
water concentration decreases
water moves from areas of ____ psi s to areas of _____ psi s
areas of ___ water [ ] —> areas of ___ water [ ]
areas of ___ solute [ ] —> areas of ___ solute [ ]
areas of ___ solute potential —> areas of ___ solute potential
higher psi s –> lower psi s
higher water [ ] —> lower water [ ]
lower solute [ ] —> higher solute [ ]
higher solute potential —> lower solute potential
water will move until the psi s is ______ on both sides
equal on both sides
osmosis in cells
plasma membranes –
cells depend on the regulated movement of ___ ___ across the PM to ___ ___
osmosis is critical to survival of cells
plasma membranes – semi-permeable barriers
cells depend on the regulated movement of water molecules across the PM to stay alive
if psi s on inside and outside of cell are equal…
water is entering and leaving the cell in equal amounts
if psi s is higher outside of a cell than inside…
water will rush into cell
cell will swell
cell could burst (lysis)
psi s is higher outside cell
water [ ] higher outside cell
solute potential higher outside
solute [ ] higher inside cell
if psi s is higher inside of a cell the outside…
water will rush out of cell
cell will shrink
cell could dehydrate and die
psi s higher inside cell
water [ ] higher inside cell
solute potential higher inside cell
solute [ ] higher outside cell
medical application of osmosis in brain
blood brain barrier keeps most medicines from entering brain
lower psi s of blood (inject solute – Mannitol) –>
water moves out of capillary wall cells –>
capillary wall cells shrink slightly and create an opening b/n cells –>
medicine can pass into brain
energy (definition)
capacity to do work
2 forms of energy:
kinetic and potential
kinetic energy (definition and examples)
energy of motion, variety of forms:
- heat, light, mechanical
potential energy (definition and examples)
stored energy:
- concentration gradients, chemical bonds
thermodynamics (definition)
branch of chemistry that deals w/ energy transformations (changes)
can be boiled down to 2 main laws:
- 1st Law of Thermodynamics
- 2nd Law of Thermodynamics
1st Law of Thermodynamics
conservation law
energy cannot be created or destroyed
energy can only change from one form of energy to another
total amount of energy in universe remains constant
2nd Law of Thermodynamics
no energy transfer is 100% efficient
some energy is always lost (usually as heat) and becomes unusable energy
entropy
unusable energy
entropy in universe is continuously increasing
free energy (definition and what is happening to free energy in universe?)
usable energy
usable energy in universe is continuously decreasing
calculating Gibbs free energy (usable energy)
G = H - TS
G = free energy, energy available to do work H = enthalpy, total amount of energy in a molecule's chem bonds (TS) = amount of disorder in a molecule T = absolute temp S = entropy, unusable energy
change in free energy after chem reactions (reactants —> products)
chem reactions begin w/ the reactants (reactants have a certain amount of free energy)
chem reactions end w/ the products (products have a certain amount of free energy)
products will either have more or less free energy than the reactants
2 types of reactions
exergonic
endergonic
what determines the type of reaction?
change in free energy
-∆G
what type of reaction is this?
exergonic reaction
products have < free energy than reactants
energy is released, can be used to do work
rxn can be spontaneous – rxn has potential to occur on its own w/o extra energy input
+∆G
what type of reaction is this?
endergonic reaction
products have > free energy than reactants
energy is absorbed – input of energy is required
never spontaneous – rxn will not occur w/o energy input
graph of endergonic rxn
G of products > G of reactants
+∆G – energy is absorbed
endergonic rxns require energy input
graph of exergonic rxn
G of products < G of reactants
-∆G – energy is released
overall net release of energy
in cells (relationship b/n ender and exergonic rxns)
free energy released by exergonic rxns can be used to drive endergonic rxns forward
reaction coupling
exergonic and endergonic rxns are coupled together
energy to drive endergonic rxns comes from exergonic rxns
ATP (definition)
adenosine triphosphate
type of nucleic acid
energy currency of cell
energy storage molecule
ATP hydrolysis
exergonic rxn
reactants – (higher free energy) ATP and H2O
products – (lower free energy) ADP + other products
-∆G – energy is released. energy is used to power endergonic rxns in a cell
structure of ATP
adenosine triphosphate
adenine (nitrogenous base)
ribose (5-carbon sugar)
3 phosphate groups (negatively charged)
hydrolysis of ATP to ADP _____ energy
releases energy
ATP –> ADP – taking away one of the phosphate groups
AMP is lowest G state
exergonic ATP hydrolysis
G of reactants > G of products
-∆G: energy is released and can be used to power an endergonic rxn
reactants: ATP & H2O
products: ADP and other products
example of coupled reactions
hydrolysis of ATP is exergonic:
ATP + H2O –> ADP + Pi
-∆G
synthesis of glutamine is endergonic:
glutamate + NH4 –> glutamine
+∆G
coupling the rxns:
reactants: glutamate + NH4 + ATP + H2O
products: glutamine + ADP + Pi
net: exergonic
ATP cycle (know the diagram)
ATP hydrolysis:
ATP + H2O –> ADP + Pi
exergonic – releases energy –> becomes energy for endergonic cellular processes
ATP synthesis:
ADP + Pi –> ATP + H2O
endergonic – requires energy –> uses energy from exergonic cellular rxns
kinetics of a rxn
rate at which rxn occurs
thermodynamics of a rxn
refers to whether energy was released or absorbed
relationship b/n TD and kinetics of a rxn
TDs say nothing about the rates of rxns
what is rate of rxn dependent on?
activation energy – how much AE is required
activation energy (definition)
amount of G required to start a chem rxn
rxns w/ high AE have ___ rate of rxn
low
rxns w/ low AE have ___ rate of rxn
high
2 components of AE
collision energy of reactants
orientation of reactants during collisions
catalysts (mechanism)
lower AE and increase rate of rxn
enzymes
biological catalysts that can:
1) hold reactants in favorable orientations
2) stress the chem bonds of reactants
enzymes ___ AE of a rxn, which makes rxn occur at ___ rate
lower AE
faster rate
4 categories of organisms (relating to energy and carbon sources)
photoautotroph
chemoautotroph
photoheterotroph
chemoautotroph
photoautotroph (energy and carbon source, examples)
energy source - light
carbon source - CO2
ex. plants & some bacteria
chemoautotroph (energy and carbon source, examples)
energy source - chemicals
carbon source - CO2
ex. some bacteria
photoheterotroph (energy and carbon source, examples)
energy source - light
carbon source - organic
ex. some bacteria
chemoheterotrophs (energy and carbon source, examples)
energy source - chemicals
carbon source - organic
ex. animals
factors in ecosystem
abiotic – nonliving
biotic – living
examples of abiotic factors
light, temp, H2O, pressure, etc.