Lecture 7. Energy and Metabolism Flashcards

1
Q

Standard free energy equation

A

ΔG = ΔG°’ + RTlnq

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2
Q

R

A

Gas constant

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3
Q

T

A

Absolute temperature in Kelvin

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4
Q

q

A

Mass action ratio

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5
Q

ΔG°’

A

Standard free energy at pH 7, 25°C and 1 atm

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6
Q

What does q = at equilibrium?

A

Keq

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7
Q

What does Keq equal at equilibrium?

A

Keq = e^-ΔG°’/2.5

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8
Q

What can relatively small changes in ΔG°’ lead to in Keq?

A

Big changes

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9
Q

What is the main energy carrier in the cell?

A

ATP

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10
Q

What is Pi?

A

Inorganic phosphate

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11
Q

What is PPi?

A

Pyrophosphate

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12
Q

What can Keq be affected by?

A

Coupling reactions

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13
Q

What happens in oxidation?

A

A compound donates electrons

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14
Q

What happens in reduction?

A

A compound accepts electrons

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15
Q

What does a strong oxidising agent want to do?

A

Accept electrons - O₂

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16
Q

What do strong reducing agents do?

A

Readily donate electrons - NADH

17
Q

What are good reductants?

A

Give of electrons even when there’s many around

18
Q

What are good oxidants?

A

Take up e⁻ even when only a few around

19
Q

What equation links redox potentials to ΔG°’?

A

ΔG°’ = -nFΔE°’

20
Q

n

A

Number of electrons

21
Q

F

A

Faraday constant

22
Q

What does a positive ΔE°’ give?

A

A negative ΔG°’

23
Q

What is ΔE°’?

A

Overall voltage of a redox reaction