Lecture 6. Metabolism Flashcards

1
Q

What is the first law of thermodynamics?

A

The total energy of a system and its surroundings is constant. Energy cannot be created or destroyed

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2
Q

What is energy?

A

The capacity to carry out change

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3
Q

What is change in energy approximately equal to in a biochemical reaction?

A

The change in enthalpy

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4
Q

What is an exothermic reaction?

A

Energy is released by the system

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5
Q

What is an endothermic reaction?

A

Energy is taken up by the system

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6
Q

What is the second law of thermodynamics?

A

Entropy is always increasing in an isolated system

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7
Q

What is the equation for Gibbs free energy?

A

ΔG = ΔH - TΔS

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8
Q

ΔG

A

Change in free energy

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9
Q

ΔH

A

Change in enthalpy

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10
Q

ΔS

A

Change in entropy

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11
Q

T

A

Temperature in Kelvin

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12
Q

What does a -ΔG mean in terms of a reaction?

A

It means the reaction is spontaneous with a loss of free energy - exergonic

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13
Q

Enthalpy equation

A

ΔH = ΔE + pΔV

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14
Q

ΔE

A

Change in energy

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15
Q

p

A

Pressure

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16
Q

V

A

Volume

17
Q

What does a +ΔH mean?

A

Reaction is endothermic

18
Q

What does a -ΔH mean?

A

Reaction is exothermic

19
Q

What does a -ΔG mean?

A

The entropy of the universe is increasing

20
Q

What does a +ΔG mean?

A

The reaction is unfavourable or not spontaneous - endergonic

21
Q

ΔG = 0

A

The system is in equilibrium - dynamic equilibirum

22
Q

Can living organism achieve overall equilibrium?

A

No

23
Q

What reaction is close to equilibrium?

A

G-6-P ⇌ F-6-P

24
Q

Does ΔG predict the reaction rates?

A

No