Lecture 5 - Carbohydrates Flashcards
What is the most common monosaccharide
glucose
What is the most common disaccharide
sucrose
How are polysaccharides stored in animals vs plants
animals = glycogen
plants = cellulose & starch
What carbon count monosaccharides are the most important for nutrition
hexoses
What are enantiomers
mirror images
What are diastereoisomers
not a mirror image
What is a chiral carbon
carbon surrounded by 4 molecules
What determines D vs L configuration
determined by the -OH group on the highest chiral carbon (furthest from carbon 1)
- if -OH is on left, its L, if -OH is on right, its D
What is the equation for the # of stereoisomers
2^n where n is the number of chiral carbons
What is Fischer projection
the linear configuration of a sugar
What is a Haworth model
the ring configuration of a sugar
What is the different between a hemiacetal and a hemiketal
hemiacetal = made from aldose
hemiketal = made from ketose
How to determine whether a sugar is alpha or beta
in Fischer, if the -OH is on the left, it will point up in Haworth, if the -OH is on the right, it will point down in Haworth
- up = beta, down = alpha
What type of bond connects monosaccharides to make a disaccharide
a glycosidic bond between 2 OH groups
What is sucrose
found in sugar cane and fruits
glucose + fructose
non-reducing - both anomeric carbons are occupied
What is lactose
found in milk
galactose + glucose
reducing
What is maltose
found in beer and liquor
glucose + glucose
reducing