Lecture 3 Flashcards
What does free energy tell you ?
- tells us if process requires or releases energy
– release of energy can be used to do cellular work: protein synthesis, folding of proteins, transport across membranes
What is a system?
- any part of universe we are studying –> anything else is surroundings
ex: you want to see how much energy it will take to lift a book in ur room (book = system; room = surrounding)
What is an isolated system?
- unable to exchange energy or matter with surroundings
What is a closed system?
– able to exchange energy, but not matter with surroundings
What is an open system?
- able to exchange energy and matter surroundings
T or F, organisms are typically open systems
True; ex: energy –> heat, matter –> waste like sweat
What are the two laws of thermodynamics state?
– 1st law: total energy of a system and its surroundings is constant. Cannot be created or destroyed, but it can be transferred –> through energy or work
– 2nd law: total entropy (disorder) of a system plus its surroundings always increases
T or F, as energy is being lost to work an equal amount of energy must be absorbed
T, think of closed system
In the case of muscle contraction ATP is used for the movement of muscle contractions, what would need to happen next in a closed system?
– ATP after being used in turn is generated from the metabolic reactions that extracted energy in the form of ATP from nutrients like carbohydrates, fats or proteins
What is a variable that can be used to measure the amount of heated released from a reaction?
- It is called enthalpy and it is the energy released or needed to break or make bonds. Enthalpy is the internal energy of the system
true or false. a reaction at equilibrium is at its lowest energy state.
true; because free energy here is = to 0
What are the three ways where entropy can be changed?
– ability of molecule to rotate/vibrate/twist around bonds
– molecules overall scattered or ordered (i.e. cell)
– larger molecules vs. smaller molecules (less entropy vs. more). –> smaller molecules would have more entropy
T or F, energy considerations determine if a reaction will proceed in one direction or occur in reverse direction
True
What is free energy dependent on?
Enthalpy and Entropy
A lot of our structures in our body are very ordered and complex. How does nature compensate for the increases order of our body?
– by increasing entropy of the surrounding