Lecture 2: Chemical Bonds and Acids & Bases Flashcards
Ionic Bonds
-Occur between metal and non-metals
-Large difference in electronegativity
-Electron is donated
Hydrophilic
water loving molecules(dissolve in water)
-Polar molecules, ions
Hydrophobic
water hating molecules (do not dissolve in water)
- Non-polar molecules
What do hydrophobic molecules do in water?
Hydrophobic molecules aggregate together when put in water to avoid destroying the hydrogen network formed by water
Acids
Donate H+ ions
-Strong acid= complete reaction
Base
-Proton (H+) acceptor
-Releases OH-
pH(potential of hydrogen)
Acids and bases are characterized by the number of protons they contain
-Negative log number of the protons is the pH
What does a buffer do?
Makes a solution resistant to pH changes(slows change in pH)
How to set up a buffer?
-Half-equivalence point(50% acid, 50% base)
-Add more H+, they will react with CH3COO- creating CH3COOH(decrease in pH)
-Add more OH-, they will react with CH3COOH creating CH3COO-(increasing pH)
Hydrophobic interactions(2 types)
- Hydrophobic interactions: hydrophobic molecules tend to aggregate together in aqueous environments
- Van Der Waals Forces: Non-polar molecules are attracted to each other due to transient dipoles
What is a transient dipole?
-When electrons are in random locations in their orbitals causing negative side to attract positive side of another atom
Ionic bonds within proteins
Ionic bonds within proteins are relatively weak
What type of acid is most important in biology?
Weak acids
Equal volumes of watery solutions and identical pH
a. contain same amount of H+ ions
b. contain the same number of water molecules
c. contain the same number of ions
d. contain solutes of the same weight
e. A and B
A
Watery solutions of identical pH and volume contain the same number of H , but not necessarily the same number of water molecules. That’s because solutions can contain widely different amounts of solutes, which in turn determines the number of water molecules (if there are more solutes, there will be less water molecules