LEC MOD 7 Flashcards
carbonyl-containing organic compound in wh9ch the carbonyl atom has at least one hydrogen atom directly attached to it; come from oxidation of primary alcohol
Aldehydes
rules in nomenclature of aldehydes:
1: parent chain
2: suffix - al
3: 1 is always the carbonyl group
4: substituents
5: when attached to a carbon ring, suffix is -carbaldehyde
carbonyl-containing compound in which carbonyl carbon atom has two other carbons directly attached to it; come from oxidation of secondary alcohol
Ketones
nomenclature for ketones”
1: parent chain
2: suffix - one
3: lowest possible number
4: substituents
5:
term to use if there is presence of ketone in a compound with multiple functional groups
oxo
physical properties of aldehydes and ketones:
POLAR
<6 C soluble, >6 C soluble in organic but not in water
higher BP
higher mol weight, hugher MP
OH and OR (alkoxy) attached to the same carbon means?
Hemiacetal formation
a formation that contains two alkoxy (OR) froup
Acetal formation
process of conversion of acetal back to aldehydes and ketones
Aceta; hydrolysis