LEC MOD 7 Flashcards

1
Q

carbonyl-containing organic compound in wh9ch the carbonyl atom has at least one hydrogen atom directly attached to it; come from oxidation of primary alcohol

A

Aldehydes

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2
Q

rules in nomenclature of aldehydes:

A

1: parent chain
2: suffix - al
3: 1 is always the carbonyl group
4: substituents
5: when attached to a carbon ring, suffix is -carbaldehyde

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3
Q

carbonyl-containing compound in which carbonyl carbon atom has two other carbons directly attached to it; come from oxidation of secondary alcohol

A

Ketones

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4
Q

nomenclature for ketones”

A

1: parent chain
2: suffix - one
3: lowest possible number
4: substituents
5:

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5
Q

term to use if there is presence of ketone in a compound with multiple functional groups

A

oxo

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6
Q

physical properties of aldehydes and ketones:

A

POLAR
<6 C soluble, >6 C soluble in organic but not in water
higher BP
higher mol weight, hugher MP

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7
Q

OH and OR (alkoxy) attached to the same carbon means?

A

Hemiacetal formation

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8
Q

a formation that contains two alkoxy (OR) froup

A

Acetal formation

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9
Q

process of conversion of acetal back to aldehydes and ketones

A

Aceta; hydrolysis

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