Lec 29 Entropy Flashcards
What type of function is entropy
State function
What is entropy
What are its units
Dispersal of matter and energy
(More combinations, more entropy)
J
Going from higher to lower entropy is spont or no spont?
What about low to high
Non spont
Spont
What is the second law of thermodynamics
For spontaneous proccess, entropy of universe must increase always
(Change always happens in direction of max entropy)
This law only tells us about Suniverse not Ssystem
When is s universe at a max and delta s equal 0
When system is at equilibrium
What factors affect entropy
Volume change of gas (more possible positions for each particle, more micro states)
Temp change: more possible energy with each particle, more possible distribution for particles
Phase changes (at constant temp):
Solid<liquid<gas
Mixing: mixing solutions increases entropy, but dissolving decreases
Increasing mols of gas:
More arrangements to more dispersal and entropy