Lec 26 Calorimetry Flashcards
What is specific heat capacity (c), what are the units
Amount of heat needed to raise temp of 1g of material by 1 degree or K (no need to convert temp)
Intensive property
J/gC* or J/gK
What does mc=
Also q/T
heat capacity (C)
What is a calorimeter
Device used to measure heat involved in chemical reaction or physical process
qrxn is equal to what in relation to a calorimeter
-q calorimeter
Heat of rxn is equal to negative heat of calorimeter
What is bomb calometry
Measuring heat at constant volume (qv)
Work =0 bc no push or pull since wall is rigid
So delta U= qv
What is Enthalpy defined as
What is it under isobaric conditions (constant pressure)
Called heat/Enthalpy of rxn
Measure of total heat content of system
H= U+PV
Isobaric: Delta H= qp
What is delta H close to in a chemical rxn
Delta U, the diff between Enthalpy change and energy change is small
Temperature is what during a phase change?
Constant then once material changes, temp increasez
When does liquid start or boil
100 degress
What is fusion and sublimation
Fusion: solid melts
Sublimation: solid to gas
What is heat capacity (C)
Amount of heat needed to raise temp of a given amount of matter by 1 degree
Units: J/C* or J/K
Extensive: amount counts