Lec 25 Thermochem Flashcards

1
Q

What is internal energy

A

Total energy of a system
U= PE+KE (on microscopic lvl)

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2
Q

What is the system

A

Part of the universe being studied

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3
Q

What is the surroundings

A

Anything not part of the system

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4
Q

What is the universe

A

System + surroundings

EVERYTHING

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5
Q

What is temperature

A

A measure of the average KE of molecules (thermal energy)

Can also be known as the quantity that determines direction of heat flow

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6
Q

Which way does heat flow when two objects are in thermal contact

A

From the hotter object to the colder object until they gain thermal equilibrium

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7
Q

Why are gasses good insulators?

A

Because heat flows better when there are more collisions, gases are always colliding

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8
Q

What is heat what are the units

A

Flow or transfer of energy due to temp difference

J or kJ

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9
Q

What is q

A

Heat that flows into a system from the surroundings

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10
Q

What happens if q is postive

A

-endothermic
-heat absorbed by system
- U increases

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11
Q

What happens if q is negative

A

-exothermic
-heat released by system
- U decreases

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12
Q

What is work

A

Force across a distance

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13
Q

When is work positive, what happens to U

A

When work is done on the system by surroundings
U increases

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14
Q

When is work negative, what happens to U

A

When work is done on surroundings by system

U decrease

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15
Q

What is U

A

Internal energy

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16
Q

What does it mean if somethings an extensive property

A

The thing depends on how much stuff you have

Ex. The amount of water L depends on how much water I have)

17
Q

What does it mean when somethings intensive

A

Amount of it doesn’t matter

Ex if you cut a block in half the density is still the same although there is less block

18
Q

What is a state function, what are examples

A

Any property where it’s value is only dependent of current state of the system, independent of history or path

Density
Entropy
Enthalpy

19
Q

What aren’t state functions, why?

A

Q and W, their values depend on how the change/process is carried out

They are extensive properties