L12 Flashcards

1
Q

what are carbohydrates?

A

polyhydroxy alcohols with aldehyde (-CHO) Or ketone (-C=O) groups and heir derivatives

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2
Q

what important roles do carbohydrates have ?

A

important structural and metabolic roles

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3
Q

how do animals obtain carbohydrates ?

A

can synthesize carbohydrates from glycogenic amino acids but most are obtained from diet

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4
Q

what is the main dietary carbohydrate?

A

strach

hydrolyzed to glucose and absorbed into blood

other sugars are converted to glucose in liver

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5
Q

what is the major metabolic fuel for all cells in the body ?

A

glucose

it is also the precursor for synthesis of other carbohydrates : glycogen for storage

ribose and deoxy ribose in nucleic acid

galactose for synthesis of lactose in milk

also found in glycolipids , glycolic proteins and proteoglycans

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6
Q

what are the functions of carbohydrates ?

A

serves as storage form of energy (ex: starch and glycogen)

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7
Q

what are the functions of glycoproteins and glycolipids ?

A

they are an important part of membrane structure and participate in functions like cell growth , adhesion , and fertilization

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8
Q

wha serves as the precursor for other biomolecules like fats and amino acids?

A

carbohydrates

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9
Q

what are the carbohydrate classifications according to number of sugar units ?

A

monosaccharides: one molecule of sugar

disaccharides : contain 2 sugars linked together

oligosaccharide : contain 3-10 monosaccharide units linked together

polysaccharide : more than 10 monosaccharides linked together

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10
Q

what are the bonds linking carbohydrates together called?

A

glycosidic bonds

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11
Q

what are the classifications of monosaccharide depending on number of carbon atoms ?

A

trioses

tetroses

pentoses

hexoses

he-roses

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12
Q

if a monosaccharide has a aldehyde group then it is a ____

A

aldoses

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13
Q

if a monosaccharide has a aldehyde group (-CHO) then it is a ____

A

aldoses

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14
Q

if a monosaccharide has a ketone group

(-C=O)it Is a ____

A

ketoses

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15
Q

what are sugar alcohols ?

A

ketone and aldehyde groups of monosaccharides reduced to alcohols

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16
Q

IMPORTANT HEXOSES :

Glucose Major fuel of life
Sugar found in Blood
Constituent of Many di and Polysaccharides

Fructose Found in fruits
Can be converted to glucose in the body

Galactose Constituent of milk Sugar (Lactose)

Mannose

A

.

17
Q

what are stereoisomers?

A

have the same structural formula but exist in different spatial arrangements ( same but opposite , like ur hands )

18
Q

what is D and L isomerism?

A

carbohydrates are either D or L isomers deepening on the position of the second to last carbon -OH

19
Q

all naturally occurring monosaccharides are ____

A

D isomers

20
Q

What is optical isomerism ?

A

monosachhardes have asymmetrical carbon atoms that deviate light and show optical activity .

+ or d means it deviates light clockwise

  • or l means it deviates like counter clockwise
21
Q

what are anomers?

A

can be seen in cyclic structure , not straight chain. anomers differ from each other in the configuration of C-1( In alcoves ) and C-2(in ketoses )

if the -OH is up then its beta

if -OH is down then it is alpha

22
Q

what are epimers ?

A

isomers that are identical but differ from each other due to variations in configuration around carbon 2, 3 , or 4 of glucose

23
Q

what are derived amino sugars ?

A

They are sugars where an -OH group is replaced by an -NH2 group.

usually takes place in carbon 2

24
Q

what are deoxy sugars ?

A

removal of oxygen from sugars

25
Q

Deoxyribose is present in DNA

6-Deoxy Galactose (Fucose) is found in many glycoproteins and glycolipids.

A

..