Kinetics I Flashcards

1
Q

describe collision theory

A

particles in gasses and liquids wont react unless
- they collide in the same direction (facing each other in the right away)
- they collide with at least a certain minimum amount of energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

define activation energy

A

the minimum amount of kinetic energy particles need to react (collide successfully- break the bonds needed to start a reaction)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what five things effect the rate of a reaction

A
  • temperature
  • surface area
  • concentration
  • pressure
  • catalysts
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

describe and explain concentration in terms of reaction rate

A

(increasing concentration of reactants increases rate of reaction)
- there are more particles in a given volume of the solution
- particles collide more frequently so have more chances to react

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

describe and explain surface area in terms of reaction rate

A

increasing surface area means more chances of collisions with surface molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

describe and explain temperature in terms of reaction rate

A

(increasing temperature increases rate of reaction)
- particles on average will have more kinetic energy
- greater proportion will have at least the activation energy and react
- greater kinetic energy means faster molecules, so there will be more collisions
(higher frequency of successful collisions)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

describe and explain temperature in terms of reaction rate

A

(increasing temperature increases rate of reaction)
- particles on average will have more kinetic energy
- greater proportion will have at least the activation energy and react
- greater kinetic energy means faster molecules, so there will be more collisions
(higher frequency of successful collisions)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

describe and explain catalysts in terms of reaction rate

A

(introduction of a catalyst increases rate of reaction)
- catalysts provide an alternative reaction pathway with a lower activation energy (provides a different way for bonds to be broken and remade)
- more particles will have sufficient energy to react

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

name the two types of catalysts

A

heterogenous and homogenous catalysts

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

describe a heterogenous catalyst

A

catalyst in a different state to reactants
- catalyst usually a solid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

name a reaction where a heterogenous catalyst it used

A

hydrogenisation of alkenes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

name the three stages of a heterogenous catalyst

A
  • adsorption
  • reaction
  • desorption
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

describe stage one in heterogenous catalysts

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly