Kinetics I Flashcards
describe collision theory
particles in gasses and liquids wont react unless
- they collide in the same direction (facing each other in the right away)
- they collide with at least a certain minimum amount of energy
define activation energy
the minimum amount of kinetic energy particles need to react (collide successfully- break the bonds needed to start a reaction)
what five things effect the rate of a reaction
- temperature
- surface area
- concentration
- pressure
- catalysts
describe and explain concentration in terms of reaction rate
(increasing concentration of reactants increases rate of reaction)
- there are more particles in a given volume of the solution
- particles collide more frequently so have more chances to react
describe and explain surface area in terms of reaction rate
increasing surface area means more chances of collisions with surface molecules
describe and explain temperature in terms of reaction rate
(increasing temperature increases rate of reaction)
- particles on average will have more kinetic energy
- greater proportion will have at least the activation energy and react
- greater kinetic energy means faster molecules, so there will be more collisions
(higher frequency of successful collisions)
describe and explain temperature in terms of reaction rate
(increasing temperature increases rate of reaction)
- particles on average will have more kinetic energy
- greater proportion will have at least the activation energy and react
- greater kinetic energy means faster molecules, so there will be more collisions
(higher frequency of successful collisions)
describe and explain catalysts in terms of reaction rate
(introduction of a catalyst increases rate of reaction)
- catalysts provide an alternative reaction pathway with a lower activation energy (provides a different way for bonds to be broken and remade)
- more particles will have sufficient energy to react
name the two types of catalysts
heterogenous and homogenous catalysts
describe a heterogenous catalyst
catalyst in a different state to reactants
- catalyst usually a solid
name a reaction where a heterogenous catalyst it used
hydrogenisation of alkenes
name the three stages of a heterogenous catalyst
- adsorption
- reaction
- desorption
describe stage one in heterogenous catalysts