Kinetics - Collision Theory Flashcards
What is the collision theory?
For a chemical reaction to take place the particles need to collide with eachother in the correct orientation with enough energy.
What is an ineffective collision?
This is when particles collide in the wrong orientation or when they don’t have enough Ea to bounce off each other without causing a chemical reaction.
What is a successful collision?
When particles collide with sufficient energy to result in a reaction
What is the collision frequency?
- the number of collision per unit time
- the more collision per unit time take place the number of particles with energy greater than the Ea increases.
What is activation energy?
- for a reaction to take place, particles need to overcome a minimum amount of energy (Ea)
What happens in exothermic reactions?
-the reactants are higher in energy than the products.
What happens in endothermic reactions?
The reactants are lower in energy than the products.
the activation energy in endothermic reactions is relatively larger than in exothermic reactions.
what is enthalpy change?
A heat change at a constant pressure
Enthalpy change in exothermic reactions
- enthalpy of the reacting system decreases
-enthalpy change is negative - energy is transferred from the reacting system to the surroundings.
Enthalpy change in endothermic reactions
-The enthalpy of the reacting system increases
- Enthalpy change is positive
- energy is transferred to the reacting system from the surroundings.
What change is this for?
Endothermic
What change is this for?
Exothermic