Kinetics - Collision Theory Flashcards

1
Q

What is the collision theory?

A

For a chemical reaction to take place the particles need to collide with eachother in the correct orientation with enough energy.

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2
Q

What is an ineffective collision?

A

This is when particles collide in the wrong orientation or when they don’t have enough Ea to bounce off each other without causing a chemical reaction.

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3
Q

What is a successful collision?

A

When particles collide with sufficient energy to result in a reaction

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4
Q

What is the collision frequency?

A
  • the number of collision per unit time
  • the more collision per unit time take place the number of particles with energy greater than the Ea increases.
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5
Q

What is activation energy?

A
  • for a reaction to take place, particles need to overcome a minimum amount of energy (Ea)
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6
Q

What happens in exothermic reactions?

A

-the reactants are higher in energy than the products.

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7
Q

What happens in endothermic reactions?

A

The reactants are lower in energy than the products.

the activation energy in endothermic reactions is relatively larger than in exothermic reactions.

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8
Q

what is enthalpy change?

A

A heat change at a constant pressure

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9
Q

Enthalpy change in exothermic reactions

A
  • enthalpy of the reacting system decreases
    -enthalpy change is negative
  • energy is transferred from the reacting system to the surroundings.
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10
Q

Enthalpy change in endothermic reactions

A

-The enthalpy of the reacting system increases
- Enthalpy change is positive
- energy is transferred to the reacting system from the surroundings.

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11
Q

What change is this for?

A

Endothermic

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12
Q

What change is this for?

A

Exothermic

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