Ketones (CnH2nO) Flashcards
1
Q
Reduction of ketones to secondary alcohols. EXAMPLE AND CONDITIONS.
A
Proanone+2[H]—>Propan-2-ol.
Conditions= NaBH4(aq) or LiAlH4(ether).
2
Q
HCN+Ketones—>2-alkyl-2-hydroxynitriles. EXAMPLE AND CONDITIONS.
A
HCN+Propanone—>2-methyl-2-hydroxypropanenitrile.
Conditions= KCN(aq) catalyst.
3
Q
Ketone reactions.
A
1.Reduction of ketones to secondary alcohols.
2.HCN+Ketones—>2-alkyl-2-hydroxynitriles.
4
Q
Ketone production methods (with conditions).
A
1.Oxidation of alkenes, conditions= hot concentrated H+/KMnO4(VII) AND R-C-R MUST BE PRESENT.
2.Oxidation of secondary alcohols, condition= H+/KMnO4(VII) AND REFLUX.