Chapter 21 Equilibria Flashcards

1
Q

Define conjugate acid–base pairs

A

Two species (an acid-base pair on each side of an acid-base equilibrium equation) that are related to each other by the difference of a hydrogen ion.

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2
Q

Define pH mathematically

A

pH = −log ([H+])

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3
Q

[H+] =

A

[H+] = 10⁻ᵖᴴ

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4
Q

Define Ka mathematically (eg. CH3COOH)

A

Ka=[H+][CH3COO-]/[CH3COOH]

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5
Q

Define pKa mathematically

A

pKa = -log(Ka)

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6
Q

Define Kw mathematically

A

Kw=[H+][OH-]

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7
Q

Define buffer solution

A

A buffer solution is a solution which resists pH changes when small amounts of acids or alkalis are added.

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8
Q

Ksp =

A

Ksp = [Ax+ (aq)]ᵃ [By- (aq)]ᵇ

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9
Q

State what is meant by the term partition coefficient Kpc

A

The ratio of the concentrations of a solute in two different immiscible solvents in contact with each other when equilibrium has been established.

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