Chapter 21 Equilibria Flashcards
Define conjugate acid–base pairs
Two species (an acid-base pair on each side of an acid-base equilibrium equation) that are related to each other by the difference of a hydrogen ion.
Define pH mathematically
pH = −log ([H+])
[H+] =
[H+] = 10⁻ᵖᴴ
Define Ka mathematically (eg. CH3COOH)
Ka=[H+][CH3COO-]/[CH3COOH]
Define pKa mathematically
pKa = -log(Ka)
Define Kw mathematically
Kw=[H+][OH-]
Define buffer solution
A buffer solution is a solution which resists pH changes when small amounts of acids or alkalis are added.
Ksp =
Ksp = [Ax+ (aq)]ᵃ [By- (aq)]ᵇ
State what is meant by the term partition coefficient Kpc
The ratio of the concentrations of a solute in two different immiscible solvents in contact with each other when equilibrium has been established.