Ionisation energy Flashcards
Define first ionisation energy
energy required to remove one electron from each atom in one mole of gaseous atoms
Define second ionisation energy
Energy required to remove one electron from one ion in one mole of gaseous ion
Whats the equation for 1st IE?
X(g) —-> X+(g) + e-
Whats the equation for 2nd IE?
X+(g) —-> X2+(g) + e-
Why does IE decrease down a group?
Atomic radius increases which means shielding increases which means theres less nuclear attraction therefore less energy is needed
Why does IE increase across a period?
Atomic radius decreases making it harder to remove an electron as nuclear charge increases (more protons) and shielding remains the same so more energy is needed
Why does atomic radius decreases across a period
Attraction between nucleus and electrons increase, outer electrons are added to the same shell so no extra shielding
Why does atomic radius increase down a group?
Extra shells are added (further away) and this means greater shielding
Why does nuclear attraction always increase?
More protons