ionisation energies Flashcards
bonding, IE's, trends in the period and group
1
Q
Ionisation energies across the period
A
INCREASES:
- nuclear charge increases
- no change in shielding or nuclear distance
- more energy required to increased attraction between valence e- and nucleus
2
Q
ionisation energies across a period - exceptions
A
groups 2&3 in periods 2&3: Be/ B and Mg/ Al
groups 5&6 in periods 2&3:
N/O and P/ S
3
Q
Why are there exceptions in Group 2&3?
A
- shielding means easier to remove electron in the 2p/ 3p sub-shell
- higher in energy level
- so further away from the nucleus so there is less attraction
4
Q
why are there exceptions in groups 5&6
A
- O and S have paired electrons in their 2p/3p sub-shells
- repulsive forces make it easier to remove since it’s less stable
5
Q
succesive ionisation energies
A
Group 1: big jump between 1&2
Group 2: big jump between 2&3
etc etc
6
Q
A