IODIMETRIC AND IODOMETRIC METHODS Flashcards
Is a direct analysis of REDUCING AGENT such as thiosulfate and arsenates by the use of IODINE
IODIMETRY
Is an indirect analysis of OXIDIZING AGENT such as ferric and cupric salts and is reduced with excess potassium iodide and the Iodine produced is titrated with a standard solution of Sodium thiosulfates.
IODIMETRY
INDICATOR IN IODIMETRY
STARCH
ASSAY OF ASCORBIC ACID:
titrant
0.1N IODINE
ASSAY OF ASCORBIC ACID:
indicator
STARCH
ASSAY OF ASCORBIC ACID:
endpoint
BLUE
ASSAY OF SODIUM HYPOCHLORITE:
titrant
0.1N SODIUM THIOSULFATE
ASSAY OF SODIUM HYPOCHLORITE:
indicator
0.1N SODIUM THIOSULFATE
ASSAY OF SODIUM HYPOCHLORITE:
endpoint
DISAPPEARANCE OF BLUE COLOR
ASSAY OF STRONG IODINE:
titrant
0.1N POTASSIUM ARSENITE
ASSAY OF STRONG IODINE:
indicator
STARCH
ASSAY OF STRONG IODINE:
endpoint
BLUE
in oxidation-reduction with 0.1N bromine (koppeshaar’s solution), ______ is employed as an oxidizing agent in the assay of aniline, phenol, & resorcinol
BROMINE
Bromine is liberated when the solution is
ACIDIFIED
ASSAY OF PHENOL:
titrant
0.1N BROMINE
ASSAY OF PHENOL:
indicator
STARCH
ASSAY OF PHENOL:
endpoint
DISAPPEARANCE OF BLUE COLOR
may be used as the oxidizing agent in the assay of iodides, arsenite and other reducing agents
POTASSIUM IODATE
The method depends upon the formation of iodine monochloride in strong HCl solution
OXIDATION-REDUCTION WITH POTASSIUM IODATE
ASSAY OF POTASSIUM IODIDE:
titrant
0.5M POTASSIUM IODATE
ASSAY OF POTASSIUM IODIDE:
indicator
STARCH
ASSAY OF POTASSIUM IODIDE:
endpoint
DISAPPEARANCE OF BLUE COLOR
The assays of sulfa drugs and other compounds containing an acrylamino group.
DIAZOTIZATION ASSAYS WITH SODIUM NITRITE