Imperfection in Solids Flashcards

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1
Q

such an
idealized solid does not exist; all contain
large numbers of various defects or

A

imperfections

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2
Q

refers to a lattice
irregularity having one or more of
its dimensions on the order of an
atomic diameter. Classification of
crystalline imperfections is
frequently made according to the
geometry or dimensionality of the
defect

A

Crystalline Defect

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3
Q

responsible for reductions of
gas pollutant emissions from

A

atomic defects

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4
Q

the simplest of the point one
normally occupied but from which an atom is missing defects

A

Vacancy or vacant lattice site

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5
Q

the presence of vacancies increases the
___ (i.e., the randomness) of the
crystal.

A

entropy

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6
Q

is an atom
from the crystal that is crowded
into an interstitial
site—a small void space that
under ordinary circumstances is
not occupied.

A

self-interstitial

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7
Q

Solids are like humans, they are not perfect. They also have ___

A

defects

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8
Q

imperfection in/of solids

A

•Point Defects
•Impurities in solids
•Linear Defects (dislocation)

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9
Q

A ___ forms when, as the solute atoms are
added to the host material, the crystal structure is
maintained and no new structures are formed.

A

solid solution

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10
Q

A solution is composed of two parts:

A

solute and a
solvent or the host

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11
Q

Impurity point defects are found in solid solutions,
of which there are two types:

A

Substitutional solid solution
2.) Interstitial solid solution

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12
Q

Appreciable quantities of a solute may be
accommodated in this type of solid solution only when
the difference in atomic radii between the two atom types is
less than about 15%. Otherwise, the solute atoms create
substantial lattice distortions and a new phase forms.

A

Atomic size factor

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13
Q

For appreciable solid solubility, the crystal
structures for metals of both atom types must be the same.

A

crystal structure

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14
Q

The more electropositive
one element and the more electronegative
the other, the greater the likelihood that they will
form an intermetallic compound instead of a
substitutional solid solution.

A

electronegativity factor

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15
Q

Other factors being equal, a metal has more of
a tendency to dissolve another metal of higher valency than
to dissolve one of a lower valency.

A

valences

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16
Q

impurity atoms fill the voids
or interstices among the
host atoms

A

Interstitial solid solution

17
Q

two types of interstitial
sites

A

tetrahedral and
octahedral

18
Q

the number of nearest
neighbor host atom

A

coordination

19
Q

___ have relatively high atomic packing
factors, which means that
these interstitial positions are relatively small.

A

metallic materials

20
Q

the maximum allowable concentration of interstitial impurity
atoms is low

A

less than 10%

21
Q

Even very small impurity atoms are ordinarily larger than the
interstitial sites, and as a consequence, they introduce some ___ on the adjacent host atoms

A

lattice strains

22
Q

(wt%) is the weight of a particular element
relative to the total alloy weight.

A

Weight percent