Imperfection in Solids Flashcards
such an
idealized solid does not exist; all contain
large numbers of various defects or
imperfections
refers to a lattice
irregularity having one or more of
its dimensions on the order of an
atomic diameter. Classification of
crystalline imperfections is
frequently made according to the
geometry or dimensionality of the
defect
Crystalline Defect
responsible for reductions of
gas pollutant emissions from
atomic defects
the simplest of the point one
normally occupied but from which an atom is missing defects
Vacancy or vacant lattice site
the presence of vacancies increases the
___ (i.e., the randomness) of the
crystal.
entropy
is an atom
from the crystal that is crowded
into an interstitial
site—a small void space that
under ordinary circumstances is
not occupied.
self-interstitial
Solids are like humans, they are not perfect. They also have ___
defects
imperfection in/of solids
•Point Defects
•Impurities in solids
•Linear Defects (dislocation)
A ___ forms when, as the solute atoms are
added to the host material, the crystal structure is
maintained and no new structures are formed.
solid solution
A solution is composed of two parts:
solute and a
solvent or the host
Impurity point defects are found in solid solutions,
of which there are two types:
Substitutional solid solution
2.) Interstitial solid solution
Appreciable quantities of a solute may be
accommodated in this type of solid solution only when
the difference in atomic radii between the two atom types is
less than about 15%. Otherwise, the solute atoms create
substantial lattice distortions and a new phase forms.
Atomic size factor
For appreciable solid solubility, the crystal
structures for metals of both atom types must be the same.
crystal structure
The more electropositive
one element and the more electronegative
the other, the greater the likelihood that they will
form an intermetallic compound instead of a
substitutional solid solution.
electronegativity factor
Other factors being equal, a metal has more of
a tendency to dissolve another metal of higher valency than
to dissolve one of a lower valency.
valences