Hydrogen Bonding Flashcards

1
Q

What is a hydrogen bond?

A

A special type of permanent dipole-dipole interaction found between certain molecules.

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2
Q

What do molecules have to have in order to have hydrogen bonding?

A

An electronegative atom, with a lone pair of electrons.

A hydrogen atom attached to an electronegative atom.

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3
Q

What does the hydrogen bond act between?

A

The lone pair of electrons on an electronegative atom and in one molecule and the hydrogen atom in a different molecule.

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4
Q

What is the strongest type of intermolecular attraction?

A

Hydrogen bonding

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5
Q

How is a hydrogen bond represented in displayed formulae?

A

As a dashed line.

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6
Q

What is the shape around the hydrogen atom involved in the hydrogen bond?

A

It is linear.

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7
Q

What type of molecule does hydrogen bonding have an significant on?

A

Water molecules.

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8
Q

Why is ice less dense than liquid?

A

Hydrogen bonds hold water molecules apart in an open lattice structure.
The water molecules are further away in ice than in water.

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9
Q

What is a benefit of ice being less dense than water?

A

It floats which provides an insulating layer for fish.

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10
Q

How many hydrogen bonds can one water molecule form?

A

4

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11
Q

Why can water molecules form 4 hydrogen bonds each?

A

There are two lone pairs on the oxygen atom and two hydrogen atoms. As there are two lone pairs of electrons, the oxygen can form two hydrogen bonds.

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12
Q

Why does water form an open tetrahedral lattice with holes?

A

The hydrogen bonds extend outwards.

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13
Q

What is the bond angle about the hydrogen that is involved in the hydrogen bond?

A

180 degrees

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14
Q

Why does water have a relatively high melting and boiling point?

A

It has London forces and hydrogen bonds so lots of energy is needed to overcome the hydrogen bonds.

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15
Q

What happens when the ice lattice breaks?

A

The rigid arrangement of hydrogen bonds is broken.

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16
Q

What happens to the hydrogen bonds when water boils?

A

The hydrogen bonds break completely.

17
Q

Name two other anomalous properties of water?

A

High surface tension and viscosity

18
Q

Why is a high surface tension and viscosity useful?

A

Insects an walk on pond water.