Electronegativity And Polarity Flashcards

1
Q

What do the nuclei of bonded atoms do in a covalent bond?

A

They attract the shared pair of electrons.

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2
Q

What happens in molecules of elements?

A

The bonded electron pair is shared evenly.

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3
Q

Why may polarity change when molecules contain different elements?
3 reasons

A

The nuclear charges are different.
The atoms may be different sizes.
The shared pair of electrons may be closer to one nucleus than the other.

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4
Q

What do the shared pair of electrons from different elements in a molecule experience?

A

More attraction from one of the bonded atoms than the other.

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5
Q

What is electronegativity?

A

The attraction of a bonded atom for the pair of electrons in a covalent bond.

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6
Q

How is electronegativity measured?

A

Using the Pauling scale.

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7
Q

What are the Pauling electronegativity values based on?

A

The periodic table.

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8
Q

What is the pattern with the Pauling electronegativity values?

A

Electronegativity increases across and up the periodic table.

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9
Q

What will happen if the electronegativity difference is large?

A

The bond will be ionic as the more electronegative atom will have a mch greater attraction for the shared pair of electrons.

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10
Q

What is the electronegativity difference for covalent bonds?

A

0

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11
Q

What is the electronegativity difference for polar covalent bond?

A

0 to 1.8

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12
Q

What is thee electronegativity difference for an ionic bond?

A

Greater than 1.8

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13
Q

What happens in a non-polar bond?

A

The bonded electron pair is shared equally between the bonded atoms.

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14
Q

What makes a bond non-polar?

A

The bonded atoms are the same or the bonded atoms or the bonded atoms have the same or similar electronegativity.

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15
Q

What is meant by the term pure covalent bond?

A

The bonded atoms come from the same element and the electron pair is shared equally.

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16
Q

Which two elements form pure covalent bonds and have very similar electronegativity?

A

Carbon and hydrogen

17
Q

What happens in a polar bond?

A

The bonded elecron pair is shared unequally between the bonded atoms.

18
Q

What is a dipole?

A

The separation of opposite charges.

19
Q

What is a permanent dipole?

A

A dipole in a covalent bond that does not change.

20
Q

Is there only ever one polar bond?

A

No, molecules containing more than two atoms can have more than one polar bond.

21
Q

What might happen if there is more than one polar bond in a molecule?

A

The dipoles may reinforce each other to create a larger dipole over the whole molecule, or cancel each other out if the dipoles act in opposite directions.

22
Q

Give an example of a polar molecule.

A

H2O

23
Q

In water, what do the two O-H bonds have?

A

A permanent dipole each.

24
Q

What do the two dipoles do in water molecules?

A

They act in different directions but do not exactly oppose each other.

25
Q

What is the charge of the oxygen atom in a water molecule?

A

Delta -

26
Q

What is the charge of hydrogen in a water molecule?

A

Delta +

27
Q

Give an example of a non-polar molecule?

A

CO2

28
Q

What do the two C=O bonds have?

A

A permanent dipole.

29
Q

What do the dipoles in CO2 do to each other?

A

They act in opposite directions and exactly oppress each other, making the molecule non-polar as the dipoles cancel each other out.

30
Q

What is the overall dipole of a non-polar molecule?

A

0