Group Properties of Elements G-IA Flashcards
Do not occur free in nature
GROUP 1A: ALKALI METALS
V ery active chemically; displace all other elements from
their chemical compound
GROUP 1A: ALKALI METALS
Oxides & hydroxides are strongly basic
GROUP 1A: ALKALI METALS
Alkali halides are soluble in water & are not hydrolyzed
GROUP 1A: ALKALI METALS
Univalent; V alence = +1
GROUP 1A: ALKALI METALS
Form simple cation; do not form complex cation with
ammonia
GROUP 1A: ALKALI METALS
All rapidly oxidized in air
GROUP 1A: ALKALI METALS
Water forming - when burned with O2
HYDROGEN (H2)
Inflammable air
HYDROGEN (H2)
Lightest element; Element common to all acids
HYDROGEN (H2)
Preparation: Lane & Messerschmidt process (99% pure
H2- conversion of water to H2 )
HYDROGEN (H2)
Three Isotopes: (same proton/ atomic number, di erent
atomic mass)
1. Protium- most abundant
2. Deuterium- heavy hydrogen (D2O: Heavy
water/ deuterated water, solvent for NMR)
3. T ritium- radioactive
HYDROGEN (H2)
Industrial uses:
○ Haber process
HYDROGEN (H2)
Industrial uses:
Gas Chromatography gas carrier/ mobile
phases (also: Helium,
- most common mobile
phase in GC; Nitrogen)
HYDROGEN (H2)
Industrial uses:
Balloon inflation
HYDROGEN (H2)
Industrial uses:
Oil hydrogenation - margarine production
HYDROGEN (H2)
Lithos (earth, rock)
LITHIUM (Li)
Lightest metal
LITHIUM (Li)
Depressant & Diuretic
(S/E: hypovolemia, hyponatremia)
LITHIUM (Li)
Mood stabilizer (sedative); DOC for
manic/bipolar disorder
(S/E: narrow Therapeutic index)
LITHIUM (Li)
Li with additive sedative effects
Li bromide
(EskalithⓇ
, LithaseⓇ
,
Quilonium-RⓇ
LITHIUM (Li)
Li carbonate
LITHIUM (Li)
Non-pharmaceutical use:
○ heat exchanger in air conditioner
LITHIUM (Li)
Non-pharmaceutical use:
○ batteries
Li
Natrium (native)
SODIUM (Na)
Cation of choice for organic meds
SODIUM (Na)
Na Promotes fluid _______
retention
Most abundant EXTRAcellular CATION
SODIUM (Na)
excess Na causes
edema
SODIUM (Na)
Kalium
POTASSIUM (K)
Potash
POTASSIUM (K)
Most abundant INTRAcellular CATION
POTASSIUM (K)
Pharmaceutical use:
○ Diuretic
POTASSIUM (K)
Pharmaceutical use:
○ For hypokalemia & muscle paralysis/ muscle
contractant (also Ca)
POTASSIUM (K)
Spectral line: red; 1861
RUBIDIUM (Rb)
Spectral line: blue; 1860
CESIUM (Cs)
Catalyst in resin polymerization
CESIUM (Cs)
1st element discovered by use of spectroscope
(Kircho -bunsen spectroscope)
CESIUM (Cs)
Francium pharma use
none
Hypothetical/ pseudo alkali metal
AMMONIUM (NH4+)
Commercial preparation: Haber’s process
AMMONIUM (NH4+)
Pharmaceutical use:
○ Diuretic
○ Expectorant
○ Buff er component
AMMONIUM (NH4+)
Ammonia cmpd:
Respiratory stimulant (pungent
odor; b a n n e da l r e a d y )
Basic (blue litmus)
Ammonia, NH3
Ammonia cmpd
10% or 16%
Household ammonia
ammonia cmpd
degree baume
Household ammonia
to neutralize
insect/ jellyfish stings
Dilute ammonia solution;
ammonia water
9.5 - 10.5% NH3
Dilute ammonia solution;
ammonia water
ammonia cmpd
27-31% NH3
Strong ammonia solution/
water
Spirit of Hartshorn
Strong ammonia solution/
water
ammonia cmpd
Composition: Strong ammonia
solution + ammonium carbonate
(others: volatile oils of nutmeg &
lemon, EtOH)
Aromatic ammonia spirit
Spirit of Sal V olatile
Aromatic ammonia spirit