Group 2 and group 7 elements Flashcards

1
Q

What happens to the first ionisation energy as you go down group 2 and why?

A

-decreases down the group
-because each element has an extra electron shell
-more shielding
-less attraction to nucleus, as further away

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2
Q

What happens to reactivity down group 2?

A

-increases
-electrons further from nucleus are easier to be lost

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3
Q

What is the general trend of melting points down group 2?

A

-decreases
-the larger the ionic radius, the further away the delocalised electrons are from the positive nuclei

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4
Q

Why does Mg not follow the general trend of melting points?

A

the arrangement of metallic ions changes

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5
Q

What products are formed when a group 2 element reacts with water?

A

metal hydroxide and hydrogen

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6
Q

Why do elements react more readily as you go down group 2?

A

ionisation energies decrease

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7
Q

What happens to the solubility of group 2 hydroxides down the group?

A

increases

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8
Q

What happens to the solubility of group 2 sulfates down the group?

A

decreases

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9
Q

How is barium sulfate used in medicine?

A

-insoluble
-opaque to x-rays
-barium meals –> diagnoses problems in oesophogus, stomach or intestines as it makes tissues look opaque

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10
Q

What is the equation for extracting titanium from its ore?

A

TiCl4(g)+2Mg(l) –> Ti(s)+2MgCl2(l)

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11
Q

What are the main properties of fluorine at room temperature?

A

-formula –> F2
-colour –> pale yellow
-physical state –> gas

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12
Q

What are the main properties of chlorine at room temperature?

A

-formula –> Cl2
-colour –> green
-physical state –> gas

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13
Q

What are the main properties of bromine at room temperature?

A

-formula –> Br2
-colour –> brown
-physical state –> liquid

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14
Q

What are the main properties of iodine at room temperature?

A

-formula –> I2
-colour –> grey
-physical state –> solid

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15
Q

Why does the boiling point of halogens increase down the group?

A

increasing strength of van der waals forces as size and relative mass of molecules increase

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16
Q

Define electronegativity.

A

the tendency of an atom to attract a bonding pair of electrons

17
Q

Why do halogens become less oxidising down the group?

A

-less reactive
-atoms become larger and the outer shell gets further from the nucleus

18
Q

What are the displacement reactions to identify chlorine?

A

-add chlorine to bromide ions
-colourless to orange

19
Q

How do you know bromine is present?

A

-add bromine to iodide ions
-orange to brown

20
Q

What is the equation for making bleach?

A

2NaOH(aq) + Cl2(g) –> NaCl(aq) + NaCl(aq) + H2O(l)

21
Q

What are the equations for chlorine and water?

A

Cl2(g) + H2O(l) <–> 2H+(aq) + Cl-(aq) + ClO-(aq)

Cl2(g) + H20(l) <–> 2H+(aq) + 2Cl-(aq) + 1/2O2(g)
(in sunlight)

22
Q

How do you test for halides?

A

-silver nitrate test
-add dilute nitric acid
-add silver nitrate solution
-precipitate formed if halide present

23
Q

Which halides produce white, cream or yellow precipitate?

A

-white –> chloride ions
-cream –> bromide ions
-yellow –> iodide ions

24
Q

What colours represent what ions in the flame tests?

A

-brick red –> calcium
-red –> strontium
-pale green –> barium

25
Q

With excess OH-, what colour precipitate does magnesium form?

A

white

26
Q

How do you test for ammonium ions?

A

-add sodium hydroxide ions
-damp red litmus paper turns blue if positive

27
Q

How do you test for sulfate ions?

A

-add dilute hydrochloric acid
-add barium chloride solution
-white precipitate forms if positive

28
Q

How do you test for hydroxide ions?

A

-pH indicator
-red litmus paper
-turns blue if positive

29
Q

How do you test for carbonate ions?

A

-add dilute hydrochloric acid
-fizz then positive

-CO2 –> use limewater
-turns cloudy if positive