General and Analytical Chemistry Flashcards

1
Q

tendency of an atom to attach to electrons

A

electronegativity

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2
Q

energy required to remove an electron in gaseous state

A

ionization energy

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3
Q

difference between intramolecular and intermolecular forces

A

intramolecular is the force between atoms while intermolecular force is between molecules

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4
Q

same element and same atomic number but different mass number

A

isotope

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5
Q

isotope with the highest mass number is said to be a

A

radioactive isotope

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6
Q

number of electrons = number of protons

T/F?

A

True

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7
Q

which group/family in the periodic table is hard and easily oxidized?

A

alkaline earth metals

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8
Q

which group from the periodic table forms soft minerals with metals?

A

chalcogens/oxygen

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9
Q

which group forms salt with metals?

A

halogen

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10
Q

which group B is considered hard, lustrous, shiny, increased density, mp and oxidation states?

A

transition metals (lanthanides and actinides)

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11
Q

shows energy level of atomic orbital

A

period/series

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12
Q

horizontal/column shows

A

which group

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13
Q

vertical/row shows

A

period/series

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14
Q

what are metalloids and state some elements

A

these are nonmetals/metals, semiconductors, can be hard to soft

metalloids are:
boron
silicon
germanium
arsenic
antimony
astatine
tellurium
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15
Q

metals are characterized as

A
good conductors
hard and lustrous
donates electrons
usually solid (only Hg is liquid)
malleable and ductile
low electronegativity & ionization state
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16
Q

nonmetals are characterized as

A

insulators
can be solid, liquid or gas
accepts electrons
high electronegativity & ionization state

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17
Q

how far the outmost electrons from the nucleus

A

atomic radius/size

18
Q

tendency to remove electrons

A

metallic character

19
Q

isoelectronic series

A

same series and same number of electrons

20
Q

radius of isoelectric series can be increased through

A

increased electrons

21
Q

in ionic compounds, what will you do to achieve neutrality between cation and anion?

A

interchange charges

22
Q

if neutrality of ionic compounds are achieved, what will you do?

A

instead of interchanging, just cancel them out

23
Q

what are oxyanions

A

oxygen atom + anions

24
Q

how to name mono and poly cation?

A

mono: as in/parent name

poly cation: -ium

25
name mono/poly anion
-ide
26
transition metals
higher: -ic lower: -ous
27
oxyanions such as bromine, iodine, chlorine
it depends on the number of oxygen such as: 1: hypo-, -ite 2: -ite 3: -ate 4: per-, -ate
28
oxyanions of nitrogen, phosphate, sulfur
higher: -ate lower: -ite ex. nitrate, nitrite
29
other oxyanions
name it with -ate
30
difference between ionic, covalent and metallic compounds
metallic: metal to metal - sea of electrons covalent: non-metals and non-metals - share electrons (nonpolar - equal sharing, polar - unequal sharing) ionic: metal to non-metal (cation and anion) - they share electrons through electrostatic attraction
31
H+ acts as cation + any anion
inorganic acids
32
how to name inorganic acids
- ite: -ous acid - ide: hydro- -ic acid - ate: -ic acid
33
explain quantum electron theory
1. electron at ground state energy level 2. absorbs quanta (definite amount of energy) 3. electron at higher energy level or excited state 4. if electron becomes lower state energy level then it emitted light
34
what are quantum number set
allowed energy levels of electrons and this usually has 4 sets of qn
35
this qn states the energy level of an electron where it is named as n= 1, 2, 3, 4,...
principal axis
36
in principal axis, as n increases what happens to the orbital and energy
orbital increases in size while energy increases
37
this qn states the orientation of the orbitals in space (-1, 0 +1)
magnetic
38
this qn states the direction spin of the electrons (+/- 1/2)
magnetic spin
39
this qn states the shape of the orbital where it is named as 0, 1, 2, 3 (s p d f)
azimuthal
40
what are the different types of radioactive decay?
``` beta alpha positron electron capture gamma ```
41
3 principles applied in filling up orbitals
aufbau, hund's, pauli's exclusion principle
42
explain aufbau, hunds & pauli's
aufbau: start rom lowest to highet energy level pauli's: no two electrons must have the same set of quantum numbers hund's: finish 1/2 before doing -1/2