added information Flashcards

1
Q

same structural formula and structure but differs in spatial agreement

A

stereoisomerism

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2
Q

nonsuperimposable mirror image; all chiral centers changed

A

enantiomers

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3
Q

one of the chiral centers changed

A

diastereomer

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4
Q

same mol. formula but differs in structure

A

structural or constitutional isomer

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5
Q

different structural isomers

A

skeletal, functional, position

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6
Q

plane symmetry; no chiral center changed aka ACHIRAL

A

meso-compound

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7
Q

nonpolar, soluble only with organic solvents, increased BP if increased mol. weight, single bonded, -ane, saturated with H

A

alkane

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8
Q

reactions of alkane

A

combustion, pyrolytic cracking, bacterial oxidation, halogenation

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9
Q

double bonded, unsaturated H, nonpolar, soluble only with org solvent, -ene, Increased BP increased mol. weight

A

alkene

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10
Q

reactions under alkene

A

bayer’s test (oxidative test), ozonolysis, markovnikov, hydrogenation

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11
Q

organic solvents used to organic functional groups

A

ether, hexane, tetrachloride

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12
Q

reacting with air/oxygen in environment therefore producing CO2 + H2O

A

combustion

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13
Q

breaking larger molecules to smaller

A

pyrolytic cracking

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14
Q

bacteria oxidizes by undergoing anaerobic process

A

bacterial oxidation

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15
Q

addition of H atoms through the use of UV light

A

halogenation

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16
Q

addition of H hydrogen to make double bonds to single bonds

A

Hydrogenation

17
Q

oxidative test where purple turns brown to detect unsaturated bonds

A

bayer’s test

18
Q

cleavage of O atoms resulting to formation of carbonyl groups

A

ozonolysis

19
Q

unsymmetrical reagent is added to unsymmetrical double bond where N goes to more substituted (contains more +) while E goes to less (contains more -)

A

markovnikov

20
Q

triple bond, unsaturated hydrocarbon, nonpolar, named with -yne

A

alkyne

21
Q

if double and triple bond are present and have the same number, always prioritize double bond

A

-enye

22
Q

makes benzene less reactive and more resistance

A

resonance stabilization

23
Q

an aromatic ring, HIGHLY nonpolar, stable due to resonance stabilization, very CARCINOGENIC

A

benzene

24
Q

benzene can be named in three different ways depending on how it was structured

A

ortho (1,2), meta (1,3), para (1,4)

25
Q

the only reaction that benzene goes through

A

EAS (electrophilic aromatic substitution)

26
Q

where H atom is replaced with electrophilic species (atoms who are electron loving)

A

EAS

27
Q

naming benzene is dependent on the following event:

A

toluene (methyl), aniline (amine), phenol (alcohol/hydroxy), anisole (methoxy/ether), benzaldehyde, benzoic acid