Gen Chem- Solubility and Rate of Reactions Flashcards
Reaction rate equation
rate= k[A]^m[B]^n
zero order reaction rate law and units
rate=k[A]^0, M.S^-1
1st order reaction rate law and units
rate= k[A]^1, S^-1
2nd order reaction rate law and units
rate= k[A]^2, M^-1.S^-1
reaction rates dependent on temperature equation
k=Ae^(-Eq/RT)
Equilibrium Constant Equation
Keq= [C]^c[D]^d/ [A]^a[B]^b
do catalysts effect the keq of a reaction
no
If K>1 for an equilibrium constant, which reaction is favored
forward reaction, product formation
If K<1 for an equilibrium constant, which reaction is favored
reverse reaction, reactant formation
If K=1 for an equilibrium constant, which reaction is favored
neither forward nor reverse is favored
what does a reaction quotient (Q) measure
measure of a reaction towards equilibrium
reaction quotient (Q) equation
Q= [C]^c[D]^d/[A]^a[B]^b
If Q>K, which reaction is favored
product formation
If Q
reactant formation
Le chatelier’s principle:
if reactant concentration increases , which shift occurs
right shift ( towards products)