Gen Chem- Solubility and Rate of Reactions Flashcards

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1
Q

Reaction rate equation

A

rate= k[A]^m[B]^n

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2
Q

zero order reaction rate law and units

A

rate=k[A]^0, M.S^-1

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3
Q

1st order reaction rate law and units

A

rate= k[A]^1, S^-1

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4
Q

2nd order reaction rate law and units

A

rate= k[A]^2, M^-1.S^-1

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5
Q

reaction rates dependent on temperature equation

A

k=Ae^(-Eq/RT)

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6
Q

Equilibrium Constant Equation

A

Keq= [C]^c[D]^d/ [A]^a[B]^b

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7
Q

do catalysts effect the keq of a reaction

A

no

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8
Q

If K>1 for an equilibrium constant, which reaction is favored

A

forward reaction, product formation

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9
Q

If K<1 for an equilibrium constant, which reaction is favored

A

reverse reaction, reactant formation

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10
Q

If K=1 for an equilibrium constant, which reaction is favored

A

neither forward nor reverse is favored

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11
Q

what does a reaction quotient (Q) measure

A

measure of a reaction towards equilibrium

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12
Q

reaction quotient (Q) equation

A

Q= [C]^c[D]^d/[A]^a[B]^b

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13
Q

If Q>K, which reaction is favored

A

product formation

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14
Q

If Q

A

reactant formation

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15
Q

Le chatelier’s principle:

if reactant concentration increases , which shift occurs

A

right shift ( towards products)

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16
Q

Le chatelier’s principle:

if product concentration increases , which shift occurs

A

left shift ( towards reactants)

17
Q

Le chatelier’s principle:

if product is removed, which shift occurs

A

right shift

18
Q

Gibbs free energy equation in relationship with equilibirum constant

A

deltaGo= -RTlnKeq

19
Q

for gibbs free energy equation w. equilibrium constant, what shift occurs with a decrease in temperature?

A

right shift