GCSE Chemistry Flashcards
Fractional Distallation
Process which separates chemicals in crude oil into useful fractions
Crude oil
A mixture of comparatively volatile liquid hydrocarbons
Contains nitrogen, sulfur, and oxygen
Hydrocarbon
Compound of hydrogen and carbon
Alkaline
Having the properties of an alkali or containing alkali
pH greater than 7
name the different fractions from crude oil
gasoline
naphtha series
kerosine oil
diesel oil
residual oil
Gasoline
Mainly used in vehicle engines
Naptha series
to dilute heavy crude oil to reduce its viscosity
Kerosene oil
burning in kerosene lamps, domestic heaters, furnaces
Diesel oil
any liquid fuel specifically designed for use in a diesel engine
Residual oil
used as a fuel for power generators or ships
how to separate crude oil into fractions in a school laboratory
Fractional distallation
Fractional distallation process
heated crude oil enters a tall fractionating column
vapours from the oil rise through the column
vapours condense when they become cool enough
liquids are led out of the column at different heights
How to classify a hydrocarbon as an alkane
Depending on the presence of double carbon bonds
state the names and molecular formula the first four alkanes
Methane - CH4
Ethane - C2H6
Propane - C3H8
Butane - C4H10
Composition of first 4 alkanes
Methane - CH4
Ethane - CH3 - CH3
Propane - CH3-CH2-CH3
Butane - CH3-2(CH2)-CH3
Describe how the trend in colour, viscosity, flammability and boiling point changes as the length of the hydrocarbon chain changes
How chain length affects
Colour - The greater the number of carbon atoms (chain length), the darker in colour that fraction is
Viscosity - increases as the number of carbon atoms (chain length) increases
Flammability - decreases with increasing molecular size
Boiling point - increases as the number of carbon atoms (chain length) increases
describe how the properties of a fraction of crude oil make it appropriate for its use
Fractional distillation is used to separate crude oil into simpler, more useful fractions
How fractional distillation is able to separate crude oil into fractions
Different hydrocarbons have different boiling points
classify the classification of a chemical as an alkane
Alkanes have the general formula CnH2n+2 can be divided into 3 groups
linear straight-chain alkanes
branched alkanes
cycloalkanes
justify the classification of a chemical as an alkane
lack of unsaturation
distinct from other compounds that also contain carbon and hydrogen
explain in detail how fractional distillation is used to separate crude oil into fractions
First crude oil is heated and most of it evaporates
It enters the fractionating column as a gas
As gas rises up the column the crude oil fractions cool and condense out at different levels, depending on their boiling points
Fractions can be used as fuels
predictions about the properties of crude oil fractions from the fraction’s hydrocarbon chain length
Each crude oil fraction contains a mixture of hydrocarbons
Properties of crude oil
density
viscosity
boiling point ranges
define complete combustion
happens in the presence of a sufficient amount of oxygen
Combustion
The process of burning something
word equation to describe the complete combustion of a hydrocarbon
Fuel + O2 → CO2 + H2O
word equation to describe the incomplete combustion of a hydrocarbon.
ethane + oxygen → carbon monoxide + carbon + water
Why is complete combustion better than incomplete
Less soot produced
More heat produced
Carbon monoxide not produced
define the process of cracking
a reaction when larger saturated hydrocarbon molecules are broken down into smaller, more useful hydrocarbon molecules
generate a word equation to describe cracking
CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH3(g)→C
1 CH3
6 CH2
1 Ch3
recognise and give examples of alkenes
Methane
propane
ethane
butane
how to test for the products of complete combustion
First a sample is weighed then burned in a furnace in the presence of excess oxygen
All of the carbon is converted to carbon dioxide, and the hydrogen is converted to water in this way
describe a chemical test to show an alkene is present
Bromine water is an orange solution of bromine
It becomes colourless when it is shaken with an alkene
justify the use of a given fuel over another
Diesel has a higher energy density than coal
Examples of fuel
wood, coal, biogas, LPG, petrol, diesel
explain in detail how the production of carbon monoxide in incomplete combustion can be lethal
When people are exposed to CO gas, the CO molecules will displace the oxygen in their bodies and lead to poisoning
Balanced symbol equations to calculate products in a combustion reaction
Fuel + O2 → CO2 + H2O
use examples to explain the process of cracking
Cracking is used in the petroleum industry to convert heavy, high-molecular weight fuels into lighter, more valuable products such as gasoline, diesel fuel, and jet fuel
Why is cracking so important to the petrochemical industry
converts larger hydrocarbons into smaller hydrocarbons, the supply of fuels is improved
Similarities between alkenes and alkanes
Both are hydrocarbons
Small alkane molecules and small alkene molecules are gases at room temperature
Both are nonpolar molecules
Both insoluble in water
Differences between alkanes and alkenes
Alkanes contain only single covalent bonds | alkenes have at least 1 double carbon-carbon bond
Alkanes are saturated hydrocarbons
alkenes are unsaturated hydrocarbons
Alkanes exhibit lower reactivity than alkenes
reaction between bromine water and an alkene
Colourless
There is no change when bromine water is mixed with an alkane, but it turns colourless when mixed with an alkene
predictions about the properties of crude oil fractions from the fraction’s hydrocarbon chain length
Properties will result in smaller chain lengths
Formation of crude oil
Formed over millions of years from the remains of tiny ancient sea animals and plants
Balanced symbol equations for cracking of alkenes
| | |
C C C C
| | | |
H H H H
Composition of crude oil
Complex mixture of hydrocarbons
what is meant by the formula
𝐶𝑛 𝐻2𝑛+2
Alkane is a saturated hydrocarbon that has Carbon-Carbon and Carbon-Hydrogen atoms that are only connected through single bonds
covalent bonds in alkanes
single covalent bonds between carbon atoms
represent alkanes by their chemical formula/molecular formula, structural or displayed formula
CnH2n+2
describe the cultural, economic and environmental impact of the oil industry around the world
Cultural - composes space and shapes culture
Economic - responsible for 12.3 million jobs at the start of this year
Environmental - damage soils and vegetation directly, and eventually groundwater
Environmental impacts of combustion fossil fuels
release nitrogen oxides into the atmosphere, which contribute to the formation of acid rain
stoichiometric calculations for combustion of fuels
H2 + ½ [O2 + 3.76N2] → H2O + 1.88N2
how to test for unsaturation
Dissolve it in 2ml of distilled water
Add bromine water dropwise with constant shaking
The given organic compound is unsaturated if the orange color of Bromine disappears
Crude oil renewable or non-renewable
Non-renewable
Where is crude oil found
ROCKS
What is molecule made or
Atoms joined together
Incomplete combustion
when there is an insufficient amount of oxygen supply