gases Flashcards

1
Q

four gaseous properties

A
  • moles (n)
  • pressure (p)
  • volume (v)
  • temperature (T)
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2
Q

moles

A
  • the amount of gas in a particular sample, in moles
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3
Q

volume

A
  • the amount of space a gas sample occupies (the volume of its container)
  • usually in L
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4
Q

pressure

A
  • force exerted over an area: the frequency and force of collisions in a gaseous system btwn particles and the container
  • atm, KPa, and torr
  • 1 atm: 760 torr/mmHg, 101 KPa
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5
Q

kinetic energy (KE)

A
  • the energy associated with the velocity of an object
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6
Q

temperature

A
  • measure of the average KE of the sample
  • temperature up, particles’ avg velocity up, pressure up in a rigid container/volume up in a fluid container
  • measured in C, but calculate in K
  • C + 273 = K
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7
Q

internal pressure

A

outward pressure on the inner walls of a container, caused by collisions between gas molecules in the sample and the walls

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8
Q

external pressures

A

inward pressure on the outer walls of the container caused by atmospheric pressure

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9
Q

temperature

A

the average kinetic energy of the center of mass of the gas sample

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10
Q

kinetic molecular theory

A

is based on the idea that matter is composed of tiny particles that are always in motion and helps explain observable properties and behaviors of gases

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11
Q

KMT postulate 1

A

gas particles move in continuous, random motion

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12
Q

KMT postulate 2

A

the volume of gas particles is negligible compared to the volume of the container

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13
Q

KMT postulate 3

A

attractive & repulsive forces between as particles are also negligible (no IMF)

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14
Q

KMT postulate 4

A

under constant temperature, there is a constant KEL perfectly elastic collisions (no energy is lost)

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15
Q

KMT postulate 5

A

the average KE of particles is proportional to the absolute temperature in K

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16
Q

simple gas laws

A

describe how 2 of the 4 gas properties are related if the other 2 are constant

17
Q

pressure & volume

A

P1V1=P2V2
- inversely proportional

18
Q

temperature & pressure

A

P1/T1=P2/T2
- directly proportional

19
Q

temperature & volume

A

V1/T1=V2/T2
- directly proportional

20
Q

moles & pressure

A

P1/N1=P2/N2
- directly proportional

21
Q

moles & volume

A

V1/N1=V2/N2
- directly proportional

22
Q

combined gas laws

A

(P1V1/N1T1)=(P2V2/N2T2)
- combines all proportionalities, cancels constants, more realistic
- for systems undergoing change

23
Q

ideal gas laws

A

PV=nRT
- R=0.08206
- an ideal gas adheres to KMT’s postulates, and for an ideal gas, PV/NT=R, the constant

24
Q

dalton’s law of partial pressure

A

total P=Pa+Pb+…
- Pa=(NaRTa)/Va, Pb…
according to KMT, the pressure of a gas depends on the pressure with the container, not other particles, so particle’s individual pressures don’t affect one another
- so each gas’s pressure can be added to find the total gas