gas laws Flashcards
perfect gas
A gas that obeys all 3 gas laws. Molecules so small they occupy no volume. Doesn’t exist, Hydrogen closest as lowest molecular weight
boyles law
at a constant temperature, volume of fixed amount of perfect gas varies inversely with its pressure
PV = K. Used Oxygen cylinder litres available in atmosphere
Charles’ law
at a constant pressure, volume of fixed amount of perfect gas varies in proportion to its absolute temperature
V/T = K
Gay-Lussac’s law
third gas law. At a constant volume, the pressure of a fixed amount of a perfect gas varies in proportion to its absolute temperature. used in hydrogen thermometer
avogadro’s hypothesis
equal volumes of gases at same temp and pressure contain equal numbers of molecules. 1 mole has 6.22 x 10 to the 23 molecules and occupies 22.4L
universal gas equation
PV = nRT, pressure, volume, amount of gas, universal gas constant, temperature
solid
molecules oscillate about mean position but arranged in tight lattice with stronge forces between them
liquid
molecules have more energy than a solid and move freely but still have attrative van der waal forces beween them
gas
molecules have enough kinetic energy to escape van der waal forces and move freely
critical temp
temp above which gas can’t be liquefied regardless of pressure
critical pressure
pressure needed to liquify gas at its critical temp
daltons law of partial pressures
in a mixture of gases the pressure each gas exerts is the same it would exert if it alone occupied the same volume