functional group name and reactivity Flashcards
alkane
c-c ethane
alkene
c=c ethene
are alkene nucleophiles?
yes . double bond attacks
alkyne
c triple bond ethyne
are alkyne nucleophiles are electrophiles?
nucleophiles
are alkynes better nucleophiles?
When a proton adds to an alkene, an alkyl cation is formed.
When a proton adds to an alkyne, a vinylic cation is formed.
A vinylic cation has a positive charge on a vinylic carbon.
It is less stable than a similarly substituted alkyl cation because the positive charge is on an sp carbon, which is more electronegative than an sp 2 carbon of an alkyl cation. This makes it less able to bear a positive charge.”
arene
ethyl benzene
are benzene nucleophile or electrophile?
nucleophile
haloalkane
chloroethane
aldehyde
final carbon
ethanal
ketone
any centre carbon
ethanone
carboxylic acid
ethanoic acid
carbonyl group
electrophile
electron sink
are carboxylic acids electrophiles or nucleophiles?
electrophile,
acid anhydride
ethanoic anhydride
are acid anhydride nucleophiles or electrophiles?
electrophilic
acyl halide
ethanoyl chloride
ester
ethyl ethanoate first part is alcohol the second is carboxylic acid
ro-c=o
is ester an electrophile or nucleophile?
electrophile
ether
methoxymethane
oxy -ane
c-o-c
are ethers nucleophiles or electrophiles
epoxides
triangle with oxygen
ethene oxide
amine
ethanamine
NR3
Amide
conh2
are amides nucleophiles
weak electrophiles
ethanamide
nitrate
o-n=o
I
o-
what are nitrates
weak nucleophiles,
nitrite
o-n=o
are nitrite nucleophiles?
ambident nucleophiles
nitrille
c triple bond n
nucleophile
nitro
r-n=o - o
nitroso
r-n=o
imine
c=n-r
imide
o=c-n-c=o
azide
methyl azide
n=n=n-r
cyanate
r-o-c= triple n
isocyanate
n=c=o
azo
r-n=n-r
thiol
r-sh
thiols are
bronsted acids
nucleophile when loses h
sulfide
r-s-r
dimethyl sulfide
sulfoxide
s=o two r groups
dimethly sulfoxide
sulfone
o=s=o two r group
dimethyl sulfone
sulfinic acid
oh-s=o r group
sulfonic acid
o=s=o -oh - r
sulfonate acid
ly
methylmethanesulfonate acid
thiocyanate
r-s-c triple n
ethyl thiocyanate
isothiocyanate
r - n= c= s
thial
r-c = s
I
h
thioketone
r-c-r
=
s
methanethione
phosphine
p R 3