functional group name and reactivity Flashcards

1
Q

alkane

A

c-c ethane

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2
Q

alkene

A

c=c ethene

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3
Q

are alkene nucleophiles?

A

yes . double bond attacks

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4
Q

alkyne

A

c triple bond ethyne

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5
Q

are alkyne nucleophiles are electrophiles?

A

nucleophiles

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6
Q

are alkynes better nucleophiles?

A

When a proton adds to an alkene, an alkyl cation is formed.

When a proton adds to an alkyne, a vinylic cation is formed.

A vinylic cation has a positive charge on a vinylic carbon.

It is less stable than a similarly substituted alkyl cation because the positive charge is on an sp carbon, which is more electronegative than an sp 2 carbon of an alkyl cation. This makes it less able to bear a positive charge.”

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7
Q

arene

A

ethyl benzene

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8
Q

are benzene nucleophile or electrophile?

A

nucleophile

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9
Q

haloalkane

A

chloroethane

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10
Q

aldehyde

A

final carbon
ethanal

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11
Q

ketone

A

any centre carbon
ethanone

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12
Q

carboxylic acid

A

ethanoic acid

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13
Q

carbonyl group

A

electrophile
electron sink

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14
Q

are carboxylic acids electrophiles or nucleophiles?

A

electrophile,

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15
Q

acid anhydride

A

ethanoic anhydride

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16
Q

are acid anhydride nucleophiles or electrophiles?

A

electrophilic

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17
Q

acyl halide

A

ethanoyl chloride

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18
Q

ester

A

ethyl ethanoate first part is alcohol the second is carboxylic acid

ro-c=o

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19
Q

is ester an electrophile or nucleophile?

A

electrophile

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20
Q

ether

A

methoxymethane

oxy -ane

c-o-c

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21
Q

are ethers nucleophiles or electrophiles

A
22
Q

epoxides

A

triangle with oxygen
ethene oxide

23
Q

amine

A

ethanamine
NR3

24
Q

Amide

A

conh2

25
Q

are amides nucleophiles

A

weak electrophiles
ethanamide

26
Q

nitrate

A

o-n=o
I
o-

27
Q

what are nitrates

A

weak nucleophiles,

28
Q

nitrite

A

o-n=o

29
Q

are nitrite nucleophiles?

A

ambident nucleophiles

30
Q

nitrille

A

c triple bond n
nucleophile

31
Q

nitro

A

r-n=o - o

32
Q

nitroso

A

r-n=o

33
Q

imine

A

c=n-r

34
Q

imide

A

o=c-n-c=o

35
Q

azide

A

methyl azide
n=n=n-r

36
Q

cyanate

A

r-o-c= triple n

37
Q

isocyanate

A

n=c=o

38
Q

azo

A

r-n=n-r

39
Q

thiol

A

r-sh

40
Q

thiols are

A

bronsted acids
nucleophile when loses h

41
Q

sulfide

A

r-s-r

dimethyl sulfide

42
Q

sulfoxide

A

s=o two r groups
dimethly sulfoxide

43
Q

sulfone

A

o=s=o two r group
dimethyl sulfone

44
Q

sulfinic acid

A

oh-s=o r group

45
Q

sulfonic acid

A

o=s=o -oh - r

46
Q

sulfonate acid

A

ly
methylmethanesulfonate acid

47
Q

thiocyanate

A

r-s-c triple n
ethyl thiocyanate

48
Q

isothiocyanate

A

r - n= c= s

49
Q

thial

A

r-c = s
I
h

50
Q

thioketone

A

r-c-r
=
s
methanethione

51
Q

phosphine

A

p R 3