enantiomers and diastomers Flashcards
what are enantiomers
they are chiral molecules that are non identical mirror images of each other. they have no plane of symmetry
nonsuperimposable
Achiral molecules are
superimposable
if a molecule has a plane of symmetry
it cannot exist as enantiomers
constitutional isomers
have the same atoms with different connectivity
stereoisomers
same connectivity, rearranged differently in space
conformation change
changes caused by bond rotation
configuration changes
changes that are caused by breaking bonds
conformation changes mean
molecules are intercovertible
stereogenic
carbon with 4 different group
racemic solution
contains stereoisomers in equal ratios
many chiral products
exist as one enantiomer
enantiomerically pure
the same enantiomer in a solution
do enantiomers have the same chemical properties?
yes
do enantiomers have the same physical properties?
yes*
they rotate plane polarised light in opposite and equal
plane polarised
a beam of light where the direction of vibration align parrerel