enantiomers and diastomers Flashcards

1
Q

what are enantiomers

A

they are chiral molecules that are non identical mirror images of each other. they have no plane of symmetry
nonsuperimposable

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2
Q

Achiral molecules are

A

superimposable

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3
Q

if a molecule has a plane of symmetry

A

it cannot exist as enantiomers

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4
Q

constitutional isomers

A

have the same atoms with different connectivity

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5
Q

stereoisomers

A

same connectivity, rearranged differently in space

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6
Q

conformation change

A

changes caused by bond rotation

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7
Q

configuration changes

A

changes that are caused by breaking bonds

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8
Q

conformation changes mean

A

molecules are intercovertible

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9
Q

stereogenic

A

carbon with 4 different group

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10
Q

racemic solution

A

contains stereoisomers in equal ratios

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11
Q

many chiral products

A

exist as one enantiomer

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12
Q

enantiomerically pure

A

the same enantiomer in a solution

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13
Q

do enantiomers have the same chemical properties?

A

yes

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14
Q

do enantiomers have the same physical properties?

A

yes*
they rotate plane polarised light in opposite and equal

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15
Q

plane polarised

A

a beam of light where the direction of vibration align parrerel

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16
Q

what are enantiomers known as

A

+ or - r or s

17
Q

diastereomers are

A

non mirror image non identical non superimposable

18
Q

cis

A

priority groups on the same side

19
Q

trans

A

priority group on opposite sides

20
Q

diastereomers can be

A

achiral

21
Q

diastereomers have

A

different physical and chemical properties

22
Q

calculate the number of stereoisomers

A

2 ^ n

23
Q

calculate the number of diastereomers

A

2 ^n-1

24
Q

meso compound

A

meso isomers are
. A meso compound is “superimposable” on its mirror image
non optically active compound

25
Q

why are meso compound inactive optically?

A

Meso form is optically inactive because the molecules in meso form have a plane of symmetry due to which the optical rotations of upper and lower parts are equal and in the opposite direction which balanced internally and compound becomes optically inactive. This property is called internal compensation.

26
Q

chiral molecules with no stereogenic centre

A

allene
it is atropisomers
the double bond will not rotate
=c=

27
Q

chiral defination

A

asymmetric in such a way that the structure and its mirror image are not superimposable

28
Q

stereogenic

A

consisting of a central atom and four distinguishable ligands such that the interchange of any two leads to a stereoisomer;

29
Q

how to seperate enantiomers

A

create diastereoisomers
they have different physical properties which makes it easier to seperate

30
Q

seperating enantiomers is called ?

A

resolution

30
Q

seperating enantiomers is called ?

A

resolution