Full Length Exam Weaknesses (C/P) Flashcards

1
Q

Introducing a catalyst lowers the

A

activation energy, always

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2
Q

How many reactants does a second order reaction have?

A

it can only have two

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3
Q

In a spontaneous reaction, we know Delta G must be <0, and therefore what must Keq be?

A

> 1

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4
Q

-log[H+] is equal to ….

A

pH

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5
Q

a very finely ground powder, suspended in a solution, but not dissolved, is known as

A

a colloid

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6
Q

molecules with hydrogen bonds have an increased boiling point or decreased?

A

increased.

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7
Q

In a neutral (uncharged) molecule, the oxidation numbers must add up to

A

zero

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8
Q

Mean Arterial Pressure at the head level but be (lesser/greater) than at the heart

A

lesser

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9
Q

During systole, elastic energy potential is stored in the ___

A

arterial wall

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10
Q

NH3 functions as a Lewis _____ because of its lone pair

A

Lewis Base

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11
Q

At STP, 1 mole of gas occupies ___- Liters

A

22.4 L

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12
Q

Most proteases are stereospecific, meaning they only cleave what form of peptides?

A

L- forms (and therefore D- amino acids display resistance to proteolysis)

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13
Q

What is the relationship between power, work and time?

A

Power (W) = Work (J) / Time (sec)

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14
Q

The molecule that is losing the electrons is referred to as the ____ agent

A

reducing

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15
Q

Is an oxidized form of a molecule one that contains a hydroxyl group or a ketone?

A

A ketone, as it has a double bond to oxygen (more bonds to oxygen)

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16
Q

Does a higher melting point mean higher or lower stability of a molecule?

A

higher stability

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17
Q

Strong acids have (strong/weak) conjugate bases

A

weak

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18
Q

Asking which compound has the most stable conjugate base is therefore also asking…..

A

which compound is the weakest acid (most stable acid)

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19
Q

What is Ohms law?

A

V= IR (voltage= current x resistance)

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20
Q

chiral centers have what sort of hybridization

A

sp3

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21
Q

What color has the shortest wavelength?

A

Violet

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22
Q

What color has the longest wavelength?

23
Q

wavelength and frequency are _____ proportional

24
Q

what color has the highest frequency?

25
in a second order reaction, rate is dependent on ______ reactant
BOTH of the reactants
26
Q is the concentration of _____
products
27
T or F; liquids do not typically undergo a large change in volume when temperature changes
T; gases, on the other hand, do change in volume-- based on temperature
28
the ____ of a sound wave is the reciprocal of the frequency
period (period and wavelength are essentially the same thing)
29
the Doppler Effect shifts ______
frequency
30
Photons (DO/ DO NOT) have a charge
do not
31
pancreatic secretions are (acidic/basic)
acidic
32
hemiacetals are present in what biological molecule
sugars
33
Decarboxylation is the loss of what functional group
-COOH
34
____ is equal to the pH when half of the compound is in a protonated form and the other half is in a deprotonated form
the pKa
35
deprotonation occurs at a higher/lower ph
higher (more basic)
36
a shorter wavelengh is equal to photons of a ____ energy
higher/larger
37
going DOWN the periodic table, nucleophilicity ____
decreases
38
The products of the Pentose-Phosphate Pathway are:
Fructose-6-phosphate Glyceraldehyde-3-phosphate NADPH Ribose-5-Phosphate
39
Amps x Time (in seconds) gives you the _____
charge
40
Centripetal force is the force pointing away from the center of a circle (T or F)
F, it is the force pointing towards the circle
41
Aromatic crown ethers are (soluble/insoluble) in water and alcohol
insoluble
42
WE know that all human amino acids have an L configuration, and this corresponds to (R) or (S) stereochemistry?
S
43
T or F; Catalysts affect Delta G
False, just activation energy
44
Would a larger atom or a smaller atom form a more stable conjugate base?
Larger
45
When converting from an aldehyde to carboxylic acid, is an oxygen gained or lost?
A bond to oxygen is gained (oxidation occurs)
46
Reverse transcriptase is used on ___
mRNA, to then create DNA
47
What causes amino acids to migrate in electrophoresis
Their charge
48
Aluminums oxidation number is always
+3
49
Hydrogen's oxidation number is *typically*, and what is the exception
+1, except when bonded to metals (LaH, NaH, CaH2) and then it's number is -1
50
Flourine's oxidation number is always
-1
51
Alkali metals oxidation number is typically
+1
52
Alkaline earth metals oxidation number is typically
+2
53
Oxygen's oxidation number is almost always
-2, except when in hydrogen peroxide (H2O2) or peroxide (O2)2- when its number is -1