Formulas, Yield and Atom Economy Flashcards

1
Q

Define empirical formula

A

The empirical formula gives the simplest whole number ratio of atoms of each element in a compound

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2
Q

Define molecular formula

A

The molecular formula gives the actual number of atoms of each element in a compound

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3
Q

What can empirical formulas be calculated from?

A

Percentage composition and from experiments

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4
Q

Define theoretical yield

A

The theoretical yield is the mass of product that should be formed in a chemical reaction

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5
Q

What does theoretical yield assume?

A

That no chemicals are ‘lost’ in the reaction

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6
Q

What can you use to calculate the theoretical yield?

A

The masses of reactants and a balanced equation

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7
Q

Will the actual yield be more or less than the theoretical yield?

A

The actual yield will always be less than the theoretical yield

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8
Q

Give reasons why the actual yield will be less than the theoretical yield?

A
  1. Starting chemicals don’t react fully
  2. Solution gets lost during transfer between containers
  3. Solution gets left on filter paper
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9
Q

How can you work out percentage yield?

A

Percentage yield = (actual yield / theoretical yield) x100

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10
Q

What doesn’t percentage yield tell you?

A

How wasteful a reaction is

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11
Q

Why could a reaction with 100% yield still be wasteful?

A

A reaction with 100% yield could still be wasteful if a lot of the atoms from the reactants end up in by-products rather than the desired product

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12
Q

What is atom economy?

A

Atom economy is a measure of the proportion of reactant atoms that become part of the desired product in the balanced chemical equation

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13
Q

What is the equation for calculating atom economy

A

% atom economy = (Mr of desired product / sum of Mr of all reactants) x100

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14
Q

How do companies use atom economies?

A

Companies in the chemical industry try to use processes with high atom economy

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15
Q

Why are higher atom economies better for the environment?

A

They produce less waste. Any waste that is made needs disposing of safely, so the less waste the better. They also make better use of raw materials, so they’re more sustainable.

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16
Q

Why are higher atom economies less expensive?

A

A company using a process with a high atom economy will spend less on separating the desired product from the waste products and also less on treating waste