Fluorine Flashcards
F
Fluorine
F-
Fluoride
Fluoride minerals
Minerals that have F- in them
What is commonly added to water for fluoridation
- sodium fluoride
- fluorosillic acid
- sodium fluoorosilicate
Non-drinking water sources of F- in diet
Fish, gelatin, tea
Natural F- gets washed into our drinking water supply by
Erosion
In 1940’s scientists found what of people who lived near water sources with F- levels lower than 1ppm
Cavaties
2/3 of Americans have
Fluorinated water
Study of medical skeletons showed
People who lived in coastal areas and ate more fish had fewer cavities
CDC study comparing kids int he late 1960s to kids in the early 1990s doing a 69% drop in what, attributed to
Cavities, either fluorinated drinking water or fluoride toothpaste
Recommended amount of daily fluoride during tooth enamel growth
0.8-1.2 ppm
Benefit of fluoride during tooth enamel formation
reduces enamel solubility - results in stronger enamel that is more resistant to bacteria
> 1.5 ppm F- per day
Tooth decay, pitting
3-6ppm F- per day
Skeletal fluorosis
Most effective public health measure for prevention of dental decay
Fluorinated drinking water
When did Calgary discontinue practice of fluorinating water
2011
Calgary drinking water 1957-1971
No fluoride
Calgary drinking water 1989-1991
Fluoride
Calgary drinking water 1998-1999
Health services recommended reduction in level of fluorine to 0.7ppm
Calgary saves this per year by not adding fluoride to water
~750,000
What has worsened in Calgary since 2011
Tooth decay in children
Negative effects of fluoride
Skeletal fluorosis, permanent tooth discolouration, joint damage
Dental fluorosis can happen when
During tooth formation
Dental fluorosis cause
Excessive fluoride exposure
Dental fluorosis effects
Children
Most crucial time for tooth formation
2 years old
Sources of fluoride that could contribute to overexposure
- mouth rinse
- ingestion of toothpaste
- bottled waters
- supplements
- public water
Responsible for 40% of all dental fluorosis
Public water fluoridation
Hardest substance in human body
Tooth enamel
Main mineral of tooth enamel
Hydroxyapatite
Hydroxyapatite
Crystalline calcium phosphate
Excess of F- combines with Ca to produce CaF-, this results in
Inadequate calcium phosphate production = less mineralization of growing enamel
Opaque, lusterless enamel
Hypomineralized
Skeletal fluorosis
Hardening of bones caused by high F- concentration
Health effects of skeletal fluorosis
- increased susceptibility to bone fractures
- thickening of bone structure
- impaired joint mobility
- ligaments and cartilage ossified
Bones are made of
Calcium phosphate
Too much F- in blood
F- leaches Ca2+ out of bones to form CaF2 which is insoluble and is flushed out of the body
Skeletal fluorosis epidemic in ___ countries
At least 25
Fluorosis is most severe in
India and China
India and China have high counts of fluorosis because
Drinking water supply (groundwater) naturally high in fluoride
6-8ppm fluoride
Present in epidemic groundwater areas in India
60 million people at risk and 6 million people disabled
20 states of India with fluorosis epidemics
Fluoride rich groundwater
Having over 1.5mg/L of naturally occurring fluoride
Mineral sources of fluoride in groundwater
Fluorite, fluorapatite, cryolite
Rock type sources of fluoride in groundwater
Igneous rock that crystallize underground - can contain fluorite and fluorapatite
Granite
Can contain fluorite and fluorapatite as it crystallizes underground
Hydrological conditions for fluoride in groundwater
Alkaline - increases solubility of F- mienrals
Phosphate fertilizers contain high levels of
F-
F- rich groundwater has more ____ than Ca
Mg
UK researchers developed what to detect fluoride in drinking water
Fast colour-changing test