Fire Assay and Metallurgy Flashcards
General prod for ore High in Silicates and Carbonates
If high amts of silicates do not add silica or borax glass. bc molten Quartz is a strong acid
If High in Sulfides, Carbonates and lead
Ground and roasted to remove sulfide fumes.
Low in lead add 12 g of litharge
Fire assaying means
quantitative det of metals inores unsing heat and dry fluxes
How is Fire assay done
Sep metals from constituents and weighing in its pure form
Au and Ag is very soluble in
Molten metallic lead
Au and Ag is completely insoluble in
Slags of suitable composition
Difference of metal bearing alloy of lead and slag
Their SG
Used to completely remove precious metals from lead
Controlled oxidizing fusion involving differential filtration
Dilute nitric acid’s (HNO3) effect on Au and Ag
Au is completely insoluble in nitric acid
Ag is soluble
What does a flux do
Converts compounds infusible a cert temp to another compound that melt at that particular temp.
Ex. Sodium carbonate lowers melting temp of quartz
What do Agents do
Dry subs for separation of metal from subs combined with it
Whys is Slag formation done
to form immiscible layers w/ diff SG to sep metals from assoc substances
What is Dore
Alloy of Gold and Silver, product of cupellation
5 Steps in Fire Assay
- Sampling
- Charging/Fluxing
- Fusion
- Cupellation
- Parting and Weighing
Purpose of using assay ton
basis for amount of ore in a charge
Why is charging/fluxing done
Ensure efficient slagging and separation
Assay crucible is used to contain it
Fusion procedure
Melt together of ore and fluxes at 1000 C for 40-50 mins
What is a Lead button
Lead with Au and Ag
What is Cupellation
Lead is separated from Dore by using cupel to absorb PbO
Composition of Cupel
Bone Ash, cement, and other refractory material
How is Ag and Au separated in “Parting”
Using Nitric acid (HNO3) to dissolve Ag and leave Au bead
What is “Inquartation”
add of known quantity of Ag to dore bead to ensure efficient parting
Griffith’s law says that…
NO Stress req for bond breakage, stress is req to prov energy to prod new surface.
What can close up cracks
Uniform compression loading
What propagates cracks
Tensile stress from differential stress
List all the gold projects
D iwata Gold project
A pex
M asbate Gold
N orth Davao Gold project
3 Benefits of Mineral Processing
F reight Savings
Improved Netal Purity
Reduced Treatment Charges
When is Batch grinding done
for lab scale or SSM
Differential Grinding means
Hard ores are ground finer than softer ones
Reduction ratio of 15-20:1
Ball mills
3 types of Rod Mills by discharge location
End Peripheral
Center Peripheral
Overflow
Kind of Ball Mill with a length much longer than its diameter
Tube Mills
2 Types of Ball mill accdg to Discharge
Grate Discharge Mill
Overflow
Discharge mill
2 Types of Ball Mills (Ball)
Standard steel ball mill
Pebble Mill
Ball Mills are often operatedin what circuit
Closed to minimize over-grinding
Reduction ratio of AG/SAG mills
250ish
AG/SAG mills with L:D of 1:3
Cascade mills
Whys is AG/SAG product good for flotation
Smooth surface means the reagents and bubbles can adsorb easier
What is used to determine capacities of equipt
Bulk Density
Advantage of Overhead eccentric
Uses less space
Dirr of Gape and Length
Gape is the dist bet the jaws, while length is width of jaw
Largest rock is what % of the gape
80%
Operation time limit for a jaw crusher
18 hrs/ day
Throw for coarse materials and for hard, brittle rocks
Longer for coarse, shorter for brittle
Capacity is measured where? Discharge capacity?
Max opening of swing jaw.
Closed side setting
Used to control feed volume of ROM of crusher
Surge Bins
Removes tramp metals from crusher
Magnetic separator
Particle size control for crusher
Grizzlies/Vibrating Screens
Regulates flow of ore to crusher
Feeder conveyor
Fixed Crushing surface in GC
Concaves
Movable Crushing surface of GC
Mantle
Vertical shaft that holds Mantle
Spindle
Sweeps out conical path for spindle
Spider
Relation of crushing force and throw
Larger crushing force, Capacity decreases though
GC capacity is measured where
Discharge zone
Delivers ore to GC
Dump trucks or Apron fed
What does scalper do
Separate fines
Storage space underneath GC
Under-Crusher hopper
Which liner is replaced more frequently in GC
Mantle
What feed char is JC effective
Blocky ores
Muddy, sticky, and wet
Ore char for GC
Slabby
Slow-crushing
Hard, abrasive minerals
Larger operating cost bet crushers
JC but higher capital cost
Taggart Crusher Selection Criteria
If Mt/hr < 161.7 x (gape in meters)^2 use JC
Maximum 2ndary Crusher feed size
15 cm
Spindle placement of CC and GC
Non-Suspended for Cone
Suspended for GC
UG drilling hole diameter
1-4 in
Surface drilling hole diameter
6- 18 in
Crushing action for CC and GC
Impact for CC
Slow Compression for GC
Feed method for CC
Non-choking
Difference of Standard and Shorthead per feed size
Standard - coarser
Short-head finer
Char of Short head CC per liner, slope of head, length of parallel sxn
Liner - Smooth
Slope - Steep
Length - Longer ii sxn
Gyradisc Crusher per deg of crushing, Crushing method, Liner angle
3rd Degree
Inter-particle
Flat angle liner
Gyrasphere Crusher per shape of crushing head and spring placement
Spherical crushing head
Why are roll crushers not used in operations
BC low feed rate due to preponderance for choking (Starvation-fed)
When are Toothed/Slugger Roll Crusher used
Softer, sticky materials
Larger Rr reqt
Crushing action of Toothed/Slugger Roll Crusher
Compression and ripping
What mat’l chars. are Hammer mill used for
mat’l wc behave plastically on slow-compression
Hammer mills use this to transfer kinetic energy to particles
Beater
When are Impactors useful
Coarser crushing
Tidco Barmac crushing mechanisms
Impact
High intensity grinding
Multi-particle pulverizing
Used for crushing coal
Coal breakers (cylindrical trommel like)
“Mechanized Mortar and Pestle used in the olden days
Stamp mills
How does a Sieve bend work
Slurry moves tangentially to curved screen
Hukki Screen works by
- Feed is fed up top, water jet from below
- Mixture is slowly rotated on Cylindrical screen
- Oversized passes thru bottom, undersized passes thru screen
How does Reciprocating Screen work
Horizontal gyratory motion stratifies and spreads material
How many products does a Gyratory screen outputs
4 (OS, 1st Grade fraction, 2nd grade fraction, Fines)
How does Morgensen Screen work
Multiple inclined screens with reduc
For removing wood chips and carbon from slurries
Delkor Linear Screen
Delkor Linear screen uses what for filtration
Multi-filament screen cloth on rollers
Classification separates based on these char
- Particle size
- SG
- Geometry
Define Viscous resistance
shear forces bet medium and mineral surface
Define Turbulent Resistance
due to displacement of fluid by mineral (eddy currents)
When does Free settling happens
Large volume of medium rel to particles (<15% solids)
Newton’s law is used for what sizes
d <= 50 microns
Stoke’s law size range
d >= 5 mm
2 minerals w/ same SG (falling velocity)
larger diameter, higher the velocity
2 minerals w/ same diameter
higher SG, higher velocity
Free settling ratio
da/db = ((Db-Df)/(Da-Df))^n
n = 0.5 for stokes n = 1.0 for Newton's law
Hindered settling condition
When pulp density is >15%
Hindered settling velocity formula
v = ksqrt(d(Ds-Dp))
Term for finers particles carried away by current
Scouring action
What does Teeter Condition mean?
when pulp density is high, each mineral is covered with thin film of water
Slurry acts as viscous fluid where only coarse particles can penetrate
How can Teeter Condition be induced
By inc pulp density thru choke points or smaller passages
In a Series sorting column w/c one has the fastest current, w/c has the largest vol
Fastest current 1st column
Largest vol last column
How do Settling cones fxn
Product is allowed to settle with the heaviest particles passing thru bot
Water is fed up top to remove the fines
What is the material in the overflow of a Rake or Spiral classifier
Fines
Material in discharge of a Rake or Spiral classifier
Coarse
Diff of Rake and Spiral classifier
Rake uses a scrapers to drag material, spiral uses a screw
Steep Spiral Classifier at steep slopes are used in what
Dewatering as well as classification
3 Factors affecting HC performance
- Diameter of vortex finder
- Mechanism of feed (Char of feed mat’l)
- Spigot diameter (overflow)
Coagulation means
altering stability of suspended colloidal solids (opposite charges attract) using London-Van der Waals forces
Flocculation means
form’t of aggregates by polymeric molecules to form bridges by taking adv of oppositely charge particlesWh
Which Coagulant pH have w/c charges
Acids +
Bases -
inorganic salts +-
What is floc
mass of particles linked together by flocculants
Explain the zones formed in thickener
Zone A - Clear solution
Zone B - Pulp of feed consistency
Zone C - Transition zone
Zone D - Pulp in compression
Upwards flow rate of thickener
Pulp feed rate - Underflow discharge rate
What are tray thickeners
Series of vertically mounted thickeners
High Capacity thickeners use this to speed up process
Flocculants
What is a Lamella Thickener
Thickener w/c uses nest of inclined plates to lower distance bu increase effective area
Solid Bowl Scroll Centrifuge uses
horizontal Screw to separate liquid and solids
Filter Medium fxb
Support for filter cake
Initial layers of cake is the true filter
How does Leaf filters work
Perforated metal framework is connected to a vacuum, this leaf will be the site cake deposition
How does Rotary Drum filter work
Horizontal drum part submerged in slurry is connected to a vacuum
Slurry is sprayed and cake is deposited due to vacuum suction
Rotation causes the cake to be scraped away
How does Disc filter work
Same as Drum but saves floor area
Horizontal belt filter works by
Slurry on a conveyor passing thru filter and washed several times to ensure collection
Tube press works by
Inflatable bladder presses slurry towards central cylindrical pump
Concentration Criterion
(Dheavy - Dfluid)/(Dlight - Dfluid)
Ease of Gravcon is high if >= 2.5
What is the dominant force acting on fine particles
Surface friction
Elutriation is the
use of water pressure from the bot to separate particles by their SG and size
What is a Warman Cyclosizer
Combination of Hydrocyclone and elutriation to hasten separation of particles
How does Jigging work
The water is lifted (pulsion) to loosen bed so heavier particles can settle thru interstices
The suction stroke presses the bed against the screen allowing more heavy fines to pass while tails overflow
Hutch water means
Constant upward vol of water to prevent compaction of bed
How do Pinched sluices and troughs
Pinched portion increases speed w/c affects the fines the most
Splitters sep fines and coarse, lights and heavies accdg to distance of throw
Pwede rin riffles ginamit
Reichert cone fxn by
Feed enters around the cone
Heavies drop thru annular slot
Humphrey Spirals are used for
Heavy mineral sands mostly
Humphrey Spiral uses wash water to
carry low density particles towards outer radius
In Shaking table, flowing flowing film affects what (SG or Size) more
Larger particles
Momentum acts on high SG more than size
Rutile is extracted for what
Titanium (TiO2)
Ilmenite formula
FeTiO3
Lithare (PbO) use and pH
Provide lead to collect metals
Strong basic flux
Use of Na2O or Soda ash
Powerful basic flux
Comb. with silicates to form slag
Use of Borax (Na2Ba4O7)
Acidic flux that lowers fusing point of slag
Use of Silica
Acidic flux. Prevent attack from fire assay crucible when caused by deficiency in silica
Use of Flour
Source of carbon
Reduction agent for litharge to lead
Nitre descrp and use
Powerful oxidizing agent
Used for sulfide ore
Particle size of ore used in fire assay
- 100 mesh or 149 microns
Concentration of Nitric acid
25% wrt to water
What is Chiddy assay
To det Au in cyanide soln
Au is ppted with lead
then Cuppelled
Scorification process
Au and Ag is dissolved w/ molten lead at high heat
Pb button and slag is formed
This is separated
Use for arsenic, bismuth, and antimony containing ores
Cupellation temp
850-1000 C
“Freezing” in fire assay
form’t of thick concentric rings of PbO
Problem bc it stops oxidation in cupellation
Speiss forms
3 Stages of Fusion
1st - preliminary heating
2nd - melting/chem rxns
3rd - quiet fusion/settling of immiscible layers
Annealing in fire assay entails:
Hammer the Dore flat while heating in flame
25% HNO3 at 1:1 ratio by vol for parting
Shallow, circular fire clay dish
Scorifier
What causes a viscous and stringy slag
Too acidic slag
Causes lumpy slag
too basic slag
Causes Unreacted reagents
Improper fluxing
lack of time and heat
Caused by low temp at 3rd stage of fusion
Improper slag/button sep
Too much or littel Pb button
improper amts of OA or RA
Cause of Non-homogenous slag
improper fluxing
Problem with Matte and Speiss
may carry Au and Ag
Corroded Crucibles cause
Silica in crucible reacts with fluxes
Prevents charge sticking to crucible
NaCl
Color of the furnace for proper fusion
dull red
Signifies Pb oxidation and absorption is proceeding efficiently
Dendritic PbO that volatilized away
Signifies end of Cupellation
Wink
- spark from the last Pb mol leaves the dore
- w/c releases latent heat
Litharge melting point
883 C
Mercury vaporizing point
369 C
What is Spelter
Impure Zinc
Ratio of weight of sample and size of ore particle
Weight of sample prop to sq of diameter of largest particle
Wt of 1st sample to total weight
5%-20%
of lines of force passing thru a unit area
Magnetic flux density or
Magnetic Induction
Force that induce lines of magnetization
Field Intensity
Intensity of Magnetizatino
Response of a material to magnetization
2 ways to remove entrained particale in Mag Sep
Alternating polarity of magnetization
Low freq vibration
In Hight Tension sep, w/c stick anmd w/c is repelled
Stick - Insulators
Repelled - Conductors
Bronze is an alloy of
Copper and Tin
Brass is an alloy of
Copper and Zinc
Crystal system of Martensite
BCT
Austenite alloy comp
Iron
Nickel
Chromium
Ferritic Stainless steel alloy
Iron and Chromium