Fatty Acids Flashcards
short chain, number carbon saturated unsaturated
Fatty Acids
Naturally occurring monocarboxylic acids with linear (unbranched) carbon chain
carboxylic acids with normally 6 carbon chain but in some instances can have 4 carbon chain
Classification of fatty acids based on chain length
Short-Chain (4-6)
Medium-Chain (8-10)
Long-chain (12-26)
Short-chain fatty acids
4-6
Medium-chain fatty acids
8-10
Long-chain fatty acids
12-26
Fatty acids can also be classified if they contain double bonds or not
Saturated - contains no double bond
Unsaturated - contains double bond
Nomenclature of fatty acids can have 3 system
IUPAC
Common Name
Genevan System
Fatty acids can be classified according to their chain length
Short-chain (4-6)
Medium-chain (8-10)
Long-chain (12-26)
Short-chain fatty acids
4-6
Medium-chain fatty acids
8-10
Long-chain fatty acids
12-26
Fatty acids can also be classified if they contain double bond or not
Saturated - does not contain double bond
Unsaturated - contains double bond
Saturated
All C-C bonds are single bonds
Types of Unsaturated Fatty Acids
Monounsaturated
Polyunsaturated
(nomenclature) Fatty acids can be named using 3 systems
IUPAC
Common Name
Genevan System
Naming of fatty acids based on common name
6 carbons - Caproic 7 carbons - Enanthoic 8 carbons - Caprylic 9 carbons - Pelargonic 10 carbons - Capric 12 carbons - Lauric 14 carbons - Myristic 16 carbons -Palmitic 18 carbons - Stearic
Genevan System
Used to differentiate saturated and unsaturated acids
Genevan System
Based on IUPAC name, just change the suffix
saturated -anoic acid
unsaturated -enoic acid
Naturally Occurring Saturated Fatty Acids
Lauric (12) Myristic (14) Palmitic (16) Stearic (18) Arachidic (20)
Lauric Acid
12 Carbon atoms
Melting point: 44 ‘C
Myristic Acid
14 Carbon atoms
Melting point: 58 ‘C
Palmitic Acid
16 Carbon atoms
Melting point: 63 ‘C
Stearic Acid
18 Carbon atoms
Melting point: 71 ‘C
Arachidic Acid
20 Carbon atoms
Melting point: 77 ‘C
In most unsaturated fatty acids, the ___ isomer predominates; the ___ isomer is rare.
Cis, Trans
Unsaturated fatty acids have ___ melting points than their saturated counterparts; the ___ the degree of unsaturation, the lower the melting point
lower; greater
Naturally Occurring Unsaturated Fatty Acids
Palmitoleic (16) Oleic (18) Linoleic (18) Linolenic (18) Arachidonic (20)
Palmitoleic Acid
16 Carbon Atoms
16:1 ^9 Degree of Unsaturation
Melting Point: -0.5 ‘C