fats + oils Flashcards
what is a triglyceride?
- molecules contain fats and oils
- large non-polar molecules
what is a triglyceride made of?
a glycerol and 3 fatty acids
how are triglycerides formed?
formed by a condensation reaction. The 3 fatty acid chains ‘connected’ to each glycerol molecule
how is the ester link formed?
by the hydroxyl group reacting with the carboxyl group.
There are 3 ester links in 1 molecule of triglyceride
what are some properties of triglycerides?
- are non-polar and unable to form H bonds with water- they are hydrophobic
- less dense than water because of the large sections of non-polar molecules
what types of fats are there?
- saturated
- unsaturated
- monounsaturated
- polyunsaturated
describe a saturated fatty acid
a fatty acid chain that has all single bonds.
describe an unsaturated fatty acid
contain one or more double or triple bonds between the molecules. These fats are liquid at room temperature in oil form.
describe a monounsaturated fatty acid
A fatty acid having one carbon-carbon double bond in its carbon chain.
describe a polyunsaturated fatty acid
more than one carbo-carbon double bond. The two major classes of polyunsaturated fats are omega-3 and omega-6 fatty acids.
what is hydrogenation?
the addition of two hydrogen atoms to unsaturated double bonds (C=C) in the fatty acid moieties of the triglycerides. The more saturated fat resulting from this reaction has a higher melting point than the starting material
describe the melting points for saturated fatty acids?
- the different melting points can be explained in terms of length and degree of saturation of their fatty acid hydrocarbon chain.
- as the hydrocarbon increases in length the melting point increases
what happens to intermolecular forces with fatty acids?
- the fatty acid tails can pack closely and so the intermolecular forces become stronger
what happens to dispersion forces with fatty acids?
the strength of the dispersion forces increase between the fatty acids molecules as the molecular mass increases
describe the melting point in unsaturated fatty acid
-when the C=C bonds increase the melting point of the unsaturated fatty acid DECREASES
do unsaturated fatty acids have weak or strong dispersion forces?
they are much weaker than those formed between saturated fatty acids
what are essential fatty acids?
unsaturated fatty acids that are essential to human health and cannot be manufactured in the body
- two types: linoleum acid and a-linoleic acid
what are nonessential fatty acids?
various amino acids that are required for normal health and growth that can be synthesised by the body
- include arachidic acid, stearic acid etc
difference between omega 3 and omega 6 fats
omega 3 refers to the the 3rd carbon atom with the first double bond from the methyl end whereas omega 6 is the same however on the 6th