Fats and Oils Flashcards
what are lipids used for in food?
frying, formation, to finished products (ex. butter on bread)
triglyceride structure:
a glycerol attached to three fatty acids
trans fatty acids have hydrogens on ___ of the double bond, cis fatty acids have hydrogen bonds on ___ of the double bond
opposite sides/the same side
linoleic: omega-___, alpha-linolenic; omega-___
6/3
physical properties are affected by:
chain length, saturation, cis/trans configuration
phospholipid structure:
glycerol, two fatty acids, one phosphate group
what are the two types of emulsions?
oil in water and water in oil
sterols
interconnected C rings with varying side chains
plant sterols are thought to do what to cholesterol?
lower it
waxes
long fatty acid and alcohol hydrocarbon chains
what are waxes used for?
coating fruits and vegetables to hold in moisture and prevent damage during transport
smoke point is lowered by:
unrefined oils, reuse
you can store MUFA/refined oils ___, PUFA/unrefined ___, refrigerate ___, ___, ___, ___
~1yr/~6mo
PUFA, butter, margarine, unrefined oils
rancidity
chemical deterioration causing off smells and flavours, caused by light, heat, and O2
what are the two types of rancidity?
hydrolytic (when exposed to water, heat, or lipase the bonds in triglycerides break) and oxidative (free radicals are formed in initiation, combined with O2 to make peroxides in propagation and used up in termination when all the H are gone)
antioxidants:
combat free radicals by being oxidized, donating H, or sequestering metals)
oil extraction is ___ (higher yield, potential nutrient loss) or ___ (either ___ or ___ pressed)
chemical
mechanical/cold/expeller
refined
chemicals and physically processed after pressing to remove any undesirable compounds
unrefined
not processed after pressing
options for refinement and what they remove:
degumming (phospholipids), neutralization (free fatty acids), bleaching (colour), deodorization (colour, flavour, free fatty acids), winterization (waxes)
hydrogenation
hardens vegetable oils by adding H to double bonds, may produce trans fatty acids
interesterification
rearrangement of fatty acid on the glycerol to change the physical properties without creating trans fatty acids
winterization
oils are cooled for a long period of time and any solids that form are removed
fractionation
a more sophisticated version of winterization with moe specific results
functions of lipids in food:
heat transfer, shortening, emulsion, flavour, texture, satiety, nutrients
tips for low fat cooking:
use nonstick pans or parchment paper, pick lean cuts, trim any visible fat, choose other cooking methods instead of frying, choose healthier fats
in baking what can be used to replace fats?
apple sauce, banana, beans, shredded zucchini, tofu
coconut oil has a middle melting point because:
high saturated fatty acids but mostly medium chains