Families of organic compounds Flashcards

1
Q

What geometry is formed when the carbon atom has 4 single bonds

A

Tetrahedral carbon

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What compounds have tetrahedral carbons?

A

alcohols and chloroalkanes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is a chloroalkane?

A

It is a compound which one or more of the hydrogen atoms in an alkane have been replaced with a chlorine atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What are example of a chloroalkane?

A

Chloromethane
Trichloromethane
1-2- Di chloropropane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

WHat are chloroalkanes used for?

A

industrial solvents- liquid at room temp

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Are chloroalkanes polar or non polar

A

They are weakly polar but are insoluble in water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is a functional group?

A

It is an atom or group of atoms which are responsible for the characteristic properties of an organic compound or series of organic compounds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What functional group do alcohols have?

A

OH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

wHAT IS A PRIMARY ALCOHOL?

A

This is where the OH functional group is bonded to only one carbon atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is a secondary alcohol?

A

This is where the OH functional group is bonded to two other carbon atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

what is a tertiary alcohol?

A

This is where the function group is bonded to three carbon atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

How is ethanol made/

A

Made by the fermentation of glucose by yeast

To prevent people drinking industrial ethanol methanol is added to denature the ethanol to make it safe to drink

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Do alcohols have a high boiling point?

A

They have a higher bOiling point than the usual alkanes due to the hydrogen bonding between alcohol molecules OH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

aRE ALCOHOLS SOLUBLE IN WATER?

A

Small alcohols are soluble in water due to the hydrogen bonding. But as the molecule gets larger the effect of the hydrogen bonding decreases so its solubility decreases

They are soluble in non polar solvents

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What is a feature of planer structures?

A

They have a double bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What are examples of planar structures?

A

aldehydes, ketones, carboxylic acids, esters, benzene compounds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Aldehydes have what functional group

A

CHO

AND THE CO BOND I DOUBLE

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Where do you position the carboxyl group in an aldeyde/

A

Always on the end of the carbon chain

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

What bonding is an a aldehyde

A

The carboxyl group has a polar bond- so aldehydes have dipole dipole forces

20
Q

What is the boiling point like for aldehydes?

A

They have a higher BP than THEIR RESPECTIVE alkanes as the dipole dipole forces between the molecules are stronger than weak van der walls forces between other alkane molecules

But is is lower than alcohols as they have hydrogen bonding

21
Q

Are aldehydes soluble in water?

A

Small aldehydes are soluble in water due to the polar carboxyl group. But as the molecule gets larger the effect of the carboxyl group decreases so its solubility decreases

22
Q

What is an aromatic aldehyde?

A

It contains a benzene ring

Benzaldehyde is a flavoruing agent and smells like almonds

23
Q

What functional group do ketones have?

24
Q

wHERE IS THE CARBOXYL GROUP FOUND IN KETONES?

A

It is found in one of the central atoms

NEVER AT THE END -ALDEHYDES ARE AT THE END

25
What is the boiling point like for ketones?
They have a higher BP than THEIR RESPECTIVE alkanes as the dipole dipole forces between the molecules are stronger than weak van der walls forces between other alkane molecules But is is lower than alcohols as they have hydrogen bonding
26
Are ketones soluble in water?
Small ketones are soluble in water due to the polar carboxyl group. But as the molecule gets larger the effect of the carboxyl group decreases so its solubility decreases
27
What is th similarity between ketones and aldehydes?
The corresponding ketone and aldehyde are structural isomers
28
what ending do ketones have?
'one' eg propanone
29
what ending do aldehydes have?
'al' eg propanal
30
What functional group do carboxylic acids have ?
COOH
31
what ending do carboxylic acids have?
'OIC-ACID' EG PROPANOIC-ACID
32
wHERE WOULD YOU USE A CARBOXYLIC ACID?
Methanoic acid found in ant and nettle stings Ethanoic acid used as a flavouring in vinegar
33
Where is the carboxylic acid group found in carboxylic acids?
COOH has a double bond between C = O and is ALWAYS FOUND ON THE END OF THE CHAIN
34
hat is the boiloing point of carboxylic acids like?
They have a higher bp than their respective alkanes, aldehydes, ketones and alcohols due to strong hydrogen bonding in the carboxylic acid molecules which are stronger than the dipole dipole and van der walls seen in other respective molecules
35
Are carboxylic acids soluble in water?
Small carboxylic acids are soluble in water due to the hydrogen bonding. But the longer the carbon chain the less of an effect the hydrogen bonding has so the carboxylic acid become less soluble
36
What ending do esters have?
'yl-ate' eg methyl ethanoate
37
What functional group do ester have?
COOC
38
How are esters formed/
Formed by reacting an alcohol with a carboxylic acid and suphuric acid being used as a catalyst condensation reaction
39
What are esters used for?
flavourings and fragrances
40
How do you name esters?
Look for the part from the carboxylic acid (contains double bond) name that Name the alcohol section and place that first in the name Remove oic acid from the carboxylic acids name and replace with oate Combine and you get eg methyl ethanoate
41
What bonding is in esters?
COOC There is dipole dipole forces
42
Are esters soluble in water/
Small esters are soluble in water due to the dipole dipole forces. But as the molecule gets larger the effect of the carboxyl group decreases so its solubility decreases
43
What do aromatic compounds contain?
Benzene ring
44
What are examples of compound containing benzene rings?
Paracetamol, cocaine and clove oil
45