Atmospheric chemistry Flashcards

1
Q

How much oxygen is there in the atmosphere as a percentage?

A

21

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2
Q

How much nitrogen is there in the atmosphere as a percentage?

A

78

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3
Q

How much CO2 is in the atmosphere as a percentage?

A

0.03

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4
Q

How much noble gases are in the atmosphere as a percentage?

A

One

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5
Q

How much H2O is in the atmosphere percentage?

A

It varies

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6
Q

What are the uses of oxygen?

A

Respiration, combustion? Oxyacetylene torches

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7
Q

What is the most reactive gas in air?

A

Oxygen

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8
Q

Is nitrogen very reactive?

A

Nitrogen is quite unreactive as it has a triple bond

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9
Q

What are the uses of nitrogen?

A

Food packaging and production of ammonia by the harbour process

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10
Q

What are the two methods of nitrogen fixation?

A

Nitrogen fixed and bacteria and lightning

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11
Q

How does nitrogen fixing bacteria convert atmospheric nitrogen to compounds that can be used by plants?

A

In the soil or in the roots of peas and beans, the nitrogen infection and bacteria convert nitrogen gas into nitrates for plants to take in their roots

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12
Q

What do plants use nitrates for?

A

To make protein for growth

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13
Q

How does lightning change atmospheric nitrogen compounds that can be used by plant plants?

A

When when lightning strikes the energy in lightning causes nitrogen and oxygen in the atmosphere to react

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14
Q

Explain using equations how lightning changes atmospheric nitrogen to nitrogen compounds

A

NO + O2—>2NO
2NO +O2 —> 2NO2
2NO2 + H20 —> HNO2 + HNO3

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15
Q

What does the nitrogen cycle show?

A

It shows the way in which nitrogen circulates in nature between air plants and animals

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16
Q

Name some in organic carbon compounds

A

Carbon monoxide and carbon dioxide

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17
Q

What is carbon monoxide

A

It is colourless odourless and tasteless
It has no effect on limitless or universal indicator

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18
Q

How does carbon monoxide form?

A

It is formed by the incomplete combustion like by insufficient oxygen supply such as in cigarettes and vehicle engines

C+1/2O2 —-> CO

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19
Q

How does carbon dioxide form?

A

By the combustion of fossil fuels
Respiration in plants and animal cells
Fermentation of glucose by yeast and anaerobic conditions

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20
Q
A
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21
Q

Describe carbon dioxide

A

It is older, less colourless and tasteless and acidic

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22
Q

Why is carbon monoxide bad?

A

It is a accumulative poison it binds to haemoglobin and prevents it working so can’t carry oxygen around in the body

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23
Q

What are the uses of carbon dioxide?

A

Photosynthesis
Fire extinguishers
Dry ice

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24
Q

What is the carbon cycle?

A

It is the way in which carbon circulates in nature between the air plants and animals

25
What is the greenhouse effect?
It is the trapping of the suns heat by particular gases in the atmosphere
26
Explain how the greenhouse effect is caused
Short ultraviolet rays from the Sun passed through the earths atmosphere and are absorbed by the Earth However, the Earth heats up and radiate heat back out in the form of long infrared rays which cannot pass through some gases in the atmosphere like carbon dioxide and water vapour so they increase the temperature of the earth
27
What is the greenhouse factor?
It measures the greenhouse effect close by a gas relative to the same amount of carbon dioxide So carbon dioxide is given a value of one
28
What is the value of CFC’s in the greenhouse factor?
Between 21,00 and 25000
29
30
What is the greenhouse factor of nitrogen oxide?
160
31
What is the greenhouse factor of carbon dioxide?
One as everything is measured relative to the same amount of carbon dioxide so it has to be one
32
What is the greenhouse factor of vapour water vapour?
0.1
33
What is the greenhouse factor of methane?
30
34
What are the effects of the greenhouse effect?
Violent weather Melting of polar ice caps Raising sea levels
35
Do we need the greenhouse effect?
Yes, we need the greenhouse effect as it is essential for life as it keeps the planet warm allowing life to exist. However we cannot have the enhanced greenhouse effect.
36
What is pollution?
It is any harmful addition to the environment
37
What is acids rain
It is rain that has a pH of less than 4.5
38
What are the causes of acid rain?
Sulphur dioxide and sulphur trioxide
39
How do sulphur dioxide form?
It is formed from the burning of sulphur and fossil fuels and from volcanoes S+02—->SO2 It is an acidic oxide and dissolves in water to form sulfurous acid SO2 + H20—> H2SO3
40
How does sulphur trioxide form?
Sulphur dioxide can be oxidised by O2 in the air just for Emma sulphur trioxide SO2+ 1/2O2 —-> SO3 Sulphur trioxide dissolved the water forms sulphuric acid SO3 + H2O—-> H2 SO4
42
Why are sulphurous acid and sulphuric acid bad?
They contribute to acid rain
43
44
What is another cause for acid rain that isn’t oxides of sulphur?
Oxides of nitrogen such as nitrogen dioxide and nitrogen monoxide
45
How do oxides of nitrogen form?
Oxides of nitrogen produced from car exhaust and power stations as nitrogen gas react with oxygen in the air nitrogen monoxide Nitrogen monoxide reacts with oxygen in the air forming nitrogen dioxide The nitrogen dioxide dissolves in water to form a mixture of nitrous acid and nitric acid
46
What are the environmental effects of acid rain?
Corrosion of limestone buildings and metal Damages trees Causes aluminium to lead out of soil into rivers causing fish to die
47
What material can be used in power stations to remove sulphur dioxide from chimney gases
Limestone in a process called scrubbing
48
What is the process called in scrubbing of chimneys to remove sulphur dioxide?
Scrubbing
49
Explain scrubbing using an equation
CaC03+ SO2–> CaCO3 + CO2 So the sulphur dioxide is removed and carbon dioxide is produced instead
50
What is ozone?
It has the molecular formula 03
51
What does the ozone do?
It screens us from harmful effects of UV radiation by absorbing the ray of the sun. UV radiation causes sunburn which can lead to skin cancer.
52
How is ozone formed?
It is formed in the stratosphere by photodissociation of oxygen E.g. the breakdown of oxygen by light
53
Explain photodissociation of oxygen in the formation of ozone
02—>O.+O. An oxygen molecule is broken down into two oxygen free radicals by light energy 02+O—->O3 Oxygen molecules in the stratosphere react with a free radical of oxygen to form ozone
54
What damage is the ozone layer?
CFC’s
55
What does CFC stand for?
Chlorofluorocarbons
56
What do CFC’s do to damage the ozone layer?
They break down and release chlorine free radicals which attack ozone in the stratosphere
57
Where do you find CFC’s?
Aerosol cans EG deodorant Fridges Air-conditioning units
58
Using equations explain how CFC attacking the ozone
CCL3F+ UV—-> CCL2F + CL. 03 + Cl. —> 02 + ClO. ClO. + O —-> Cl. + O2
59