Extraction Of Metals Flashcards
What are properties of metals?
- solid at room temperature with high melting and boiling points
- shiny
- malleable
- good conductors of heat and electricity
- ductile
- metals form ionic compounds and become positive ions
Describe the structure in metals:
Metallic bonding
- regular arrangement of positive charged metal ions, surrounded by a sea of delocalised electrons
- the higher the charge the stronger the bond
How does the structure of metals mean that they have a high melting and boiling point?
- force of attraction between the positive ions and delocalised electrons is very strong because their electrical charges are opposite
- this strong force is difficult to overcome, so they only melt at a relatively high temperature
How does the structure of metals mean that they conduct electricity and heat well?
Metals will conduct electricity when solid due to the delocalised electrons that are able to move and carry the charge.
How does the structure of metals mean that they are malleable?
Pure metals have a regular arrangement which allows layers to slide over each other without breaking apart.
Define malleable:
Being able to bend without breaking
Why’re metals strong?
The attraction between the positive ions and delocalised electrons is very strong so they’re very strong.
What are the properties of alloys and why are they different?
Alloys are harder, stronger and less malleable
Because they have atoms of different sizes so the atom arrangement is irregular
What’s the reactivity series?
Potassium (potato) Sodium (soup) Lithium (lives) Calcium (calmly) Magnesium (mearly) Aluminium (always) Carbon (could) Zinc (zoos) Iron (in) Tin (tiny) Lead (leek) Hydrogen (hear) Copper (Chester) Silver (stupid) Gold (girls) Platinum (preach)
Define ore:
Rocks that contain enough metal to make it worth extracting.
Which elements use electrolysis for extracting metals? And what’s electrolysis?
Potassium, sodium, lithium, calcium, magnesium, aluminium
-Reactive metals are extracted by using electricity to decompose the metal ore
Which elements use carbon for extracting metals? And how is carbon used?
Carbon, zinc, iron, tin, lead, hydrogen, copper
- copper is very cheap and readily available
- more reactive than a number of metals and therefore it’s possible to perform displacement reactions using it
What’s the process for extracting the least reactive metals?
Silver, gold, platinum
-least reactive metals in the earths crust they exist in their native state
How’s iron extracted from its ore in a blast furnace?
Coke
Iron Ore
Limestone
-to produce a high temperature coke reacts with the hot air(oxygen) to produce carbon dioxide and heat
-then the carbon dioxide reacts with coke to produce carbon monoxide
-then carbon monoxide reacts with the iron ore to produce iron
What’s the reducing agent in the reaction between carbon monoxide and iron ore?
Carbon monoxide is the reducing agent
-it’s a good reducing agent because it’s a gas so it completely surrounds the solid particles or iron ore
What’s another name for iron ore?
Haematite
Define alloy:
A mixture of two metals
What’re uses of a mild steel/low carbon steel?
Contains small amounts of other transition elements but mainly carbon up to 0.25%
-the steel is malleable enough to be shaped(car bodies) but quite tough
What’re uses of a high carbon steel?
Contains up to 2% carbon
-far less malleable than low carbon steel, used to make strings and strong cables
What’re uses of a ultra-high carbon steel?
- contains up to 3.5% carbon
- steels are even harder and are used for tools such as axes, chisels and knife blades
What’re uses of a stainless steel?
- quite expensive to make as it contains costly transition elements such as chromium and nickel
- it doesn’t rust, it’s used for cutlery
Define painting or greasing as a prevention of rusting:
Cheap but not terribly effective
This prevents water and oxygen from coming into contact with the iron
Define sacrificial protection as a prevention of rusting:
-a block of more reactive metal is attached to the iron, since the blocks more reactive it’ll react first leaving the iron unaffected
Define galvanising as a prevention of rusting:
- covering iron/steel with a thin layer of zinc
- it’s sacrificial protection using zinc, because zinc is more reactive zinc reacts with the oxygen instead
Define alloying as a prevention of rusting:
More expensive but effective, an example being stainless steel
What two substances are needed for iron to rust? And what speeds up the reaction?
Water
Oxygen
Speeds up reaction: salt
How is aluminium extracted by electrolysis?
Aluminium is dissolved in cryolite to lower the melting point of the bauxite(aluminium oxide)
- at the anode(+) oxide ions lose electrons and the oxygen reacts with the anode so the anode erodes
- at the cathode(-) aluminium ions gain electrons
Why is aluminium so useful?
- low density
- very ductile and malleable
- conducts electricity well
- resists corrosion
What’s oxidation?
Oxidation is the losing of electrons or the gaining of oxygen.
What’s reduction?
Reduction is the gaining of electrons or the lose of oxygen.
Why do redox reactions always happen?
Because oxidation and reduction always happen at the same time