Equillibrium Flashcards

1
Q

When a chemical equilibrium is established..

A

Both the reactants and the products are present at all times
The equilibrium can be approached from either sides
The reaction is dynamic
The concentration of reactants and products remain constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

At a constant temp the calculation would be

A

[C] c [D]^d / [A]^a [B]^b = a constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is the value of kc (constant) affected by

A

Change of temperature nothing else

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Equilibrium mixture

A

Mixture of reactants and products in which the proportions of the components remain constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Kc

A

Represents the relationship between products and reactants of a reaction at equilibrium

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What equilibrium contsants should require

A

1) requires a homogeneous reaction where products and reactants are in the same physical state
2)you do not include solids
3)the units may be different for each reaction
4)kc varies with temperature but not icncentrarion or pressure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

A value of kc less than 1

A

Equilibrium position is towards reactants the smaller the value of kc the further it lies on the left

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

A kc value of 1

A

Equilibrium shifts position half way between reactants and products

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

A kc value more than 1

A

Equilibrium position towards products
The larger the value of kc the further it lies to the right

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Temp inc
Subsystem oppose
Endo
Yield ammonia decreases

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

calculating moles at equilibrium

A

moles of reactants at equilibrium = initial moles - reacted moles

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

calculations involving kc

A

1)construct the balanced equation including state symbols
2)determine the number of moles of each species at equilibrium
3)divide moles by volume to get the equilibrium concentrations in mol dm-3
4)from the equation constructed in the first step write out an expression for kc
5)subsiritue values from third step and calculate the value of Kc with any units

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

what is a homogenous reaction

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

CHANGING THE TEMP ON KC

A

-changes value of kc
-as the equillibrium consentrations of the prodicts and recatants change
-if you get more products kc rises if you get less product kc decreases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

increasing temp in in exo

A

decreases ewuillibrium constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q
A