Equillibrium Flashcards
When a chemical equilibrium is established..
Both the reactants and the products are present at all times
The equilibrium can be approached from either sides
The reaction is dynamic
The concentration of reactants and products remain constant
At a constant temp the calculation would be
[C] c [D]^d / [A]^a [B]^b = a constant
What is the value of kc (constant) affected by
Change of temperature nothing else
Equilibrium mixture
Mixture of reactants and products in which the proportions of the components remain constant
Kc
Represents the relationship between products and reactants of a reaction at equilibrium
What equilibrium contsants should require
1) requires a homogeneous reaction where products and reactants are in the same physical state
2)you do not include solids
3)the units may be different for each reaction
4)kc varies with temperature but not icncentrarion or pressure
A value of kc less than 1
Equilibrium position is towards reactants the smaller the value of kc the further it lies on the left
A kc value of 1
Equilibrium shifts position half way between reactants and products
A kc value more than 1
Equilibrium position towards products
The larger the value of kc the further it lies to the right
Temp inc
Subsystem oppose
Endo
Yield ammonia decreases
calculating moles at equilibrium
moles of reactants at equilibrium = initial moles - reacted moles
calculations involving kc
1)construct the balanced equation including state symbols
2)determine the number of moles of each species at equilibrium
3)divide moles by volume to get the equilibrium concentrations in mol dm-3
4)from the equation constructed in the first step write out an expression for kc
5)subsiritue values from third step and calculate the value of Kc with any units
what is a homogenous reaction
CHANGING THE TEMP ON KC
-changes value of kc
-as the equillibrium consentrations of the prodicts and recatants change
-if you get more products kc rises if you get less product kc decreases
increasing temp in in exo
decreases ewuillibrium constant