Equilibrium Constant - Equilibria Pt A - (4.2) Flashcards
What is the equilibrium constant?
A constant that describes the ratio of products & reactants in a given equilibrium at a given temperature
How is the equilibrium constant represented in an equation?
Kc
Give the general equation for finding Kc
Kc = concentration of products/concentration of reactants
-Add exponents from reaction stoichiometry (e.g in the equation if reactant is 2R in the equation it would be [R]^2)
- Multiply the concentration of reactants together (do same for products) e.g if A+2B -> C,
Kc = [C]/[A][B]^2
What does it mean if Kc is large (>1)?
- The concentration of products is larger than that of the reactants
- The equilibrium lies to the right
What does it mean if Kc is small (<1)?
- The concentration of the reactants is larger than that of products
- The equilibrium lies on the left
What factors do affect the value of Kc?
Only change in temperature - the effect of changing the temperature is that the concentration of one side increases & the other decreases
What factors do not affect the value of Kc?
- Changing concentration
- Changing pressure
(For both these factors the equilibrium will shift to restore the ratio of Kc) - Catalyst
(does not effect the equilibrium so does not affect Kc)