Enthalpy definitions Flashcards
Enthalpy of formation
enthalpy change that occurs when one mole of a compound is formed from its elements
Enthalpy of combustion
enthalpy change that occurs when one mole of a substance undergoes complete combustion in excess oxygen
Enthalpy of bond dissociation
enthalpy change when one mole of covalent bonds in a gaseous molecule is broken to form gaseous atoms (free radicals)
Enthalpy of atomisation
enthalpy change when one mole of gaseous atoms is produced from an element in its standard state
1st ionisation energy
enthalpy change when one mole of gaseous atoms each loose one electron to produce one mole of gaseous 1+ ions and electrons
1st electron affinity
enthalpy change accompanying the addition of one electron to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions
Lattice enthalpy
enthalpy change that accompanies the formation of one mole of a solid ionic compound is formed from its consituent isolated gaseous ions under standard conditions
Enthalpy of lattice dissociation
enthalpy change when one mole of a solid ionic compound is split into isolated gaseous ions
Enthalpy of hydration
standard enthalpy change that takes place when one mole of isolated gaseous ions is dissolved in water to form one mole of aqueous ions
Enthalpy of solution
standard enthalpy change that takes place when one mole of a compound is completely dissolved in water under standard conditions