Energy Changes Flashcards
Exothermic reaction
Heat is given out, this shown in a temperature rise
The best example of exothermic reaction is burning fuels - also called combustion.
Endothermic reaction
Heat is taken. Shown in a fall in temperature.
Examples of this could be thermal decomposition
Or reaction between citric acid and sodium hydrogencarbonate
How to measure energy transferred by a chemical reaction?
By taking the temperature of the reagents, mixing them in a polystyrene cup and measuring the temperature of the solution at the end of the reaction
Method for energy transferred practical
1) put 25cm^3 of 0.25 mol/dm^3 of hydrochloric acid and sodium hydroxide in separate beakers.
2) place the beakers in a water bath set to 25 degrees until they are both at the same temperature .
3) add the HCl followed by the NaOH to a polystyrene cup with a lid.
4) take the temperature of the mixture every 30 seconds, and record the highest temperature.
5) repeat steps 1-4 using 0.5mol/dm^3 and then 1 mol/dm^3 of hydrochloric acid
What is a reaction profile
Shows energy changes
Bond energies
Energy must always be supplied to break existing bonds - endothermic
Energy is released when new bonds are formed - exothermic
Chemical reactions in a cel produce
Electricity
The voltage of a cell depends on many factors. Name the factors
Different metals
Type of electrode
In non rechargeable batteries what happens?
Reactants get used up and turned into the products of the reaction. Once any one of the reactants is used up, the reaction can’t happen and so electricity is produced. The products can’t be turned back into the reactants, so the cell cant be recharged.
Fuel cells
Use fuel and oxygen to produce electrical energy
Hydrogen-oxygen fuel cells
Involves a redox reaction.
At the negative electrode (anode), hydrogen loses electrons to produce H+ ions. This is oxidation.
At the positive electrode (cathode), oxygen gains electrons from the cathode and reacts with H+ ions to make water. This is reduction
Uses of Hydrogen-oxygen fuel cells
Could be used in vehicles because:
It does not produce as many pollutants as other fuels
Only by products are water and heat
Batteries are more expensive to make then fuel cells
Batteries also store less energy, so they must be recharged a-lot more often