Energetics Flashcards
What is potential and kinetic energy:?
Is the energy due to the position of the particles
Is the energy associated with the movement of particles
What is the heat content/enthalpy?
Is the total amount of energy in chemicals
What is the enthalpy change?
is the heat energy measured at constant pressure with the symbol of kJ mol-1
What is the system and surroundings?
System- is the chemical products and reactants
Surroundings- is the parts that do not take part in the reaction, anything dipping into the reaction mixture eg thermometer
What is the definition of an endothermic and exothermic reaction?
Is the energy absorbed from the surroundings, surroundings decrease in temperature
Is the energy released to the surroundings, surroundings increase in temperature
What are 2 differences between endothermic and exothermic reactions?
Breaking the bond between 2 atoms require energy, making the bond between 2 atoms releases energy
If the energy absorbed for bond breaking is greater than the energy released in making new bonds, if the energy absorbed for bond breaking is less than the energy released in making new bonds
What is bond energy/bond dissociation energy?
Is the total amount of energy needed to break one mole of a particular bond in one mole of gaseous molecules. Symbol is E
What is the standard enthalpy change of reaction, combustion, neutralisation and solution?
is the enthalpy change when the amount of reactants shown in the solution react to give products
is when 1 mole of a substance is burnt in excess oxygen
relates to the enthalpy change for the reaction
when 1 mole of a substance dissolve to from a dilute solution in water
What is the standard enthalpy change of formation?
refers to the formation of 1 mole of a compound from its element under standard conditions
State Hess’s law
states the total amount of enthalpy change for a chemical reaction is independent of the route by which the reaction proceeds
What is the standard enthalpy change of hydration
is when 1 mole of gaseous ions dissolves in water to form a dilute solution
What is lattice energy?
is when 1 mole of an ionic compound is formed from its gaseous ions
What is the enthalpy change of atomisation?
is the enthalpy change when 1 mole of gaseous atoms informed from the element
What is the definition of electron affinity?
is the enthalpy change when 1 mole of electrons is added to 1 mole of gaseous atoms
What’s the born haber cycle?
is an enthalpy cycle which includes the enthalpy changes