ENERGETIC, II. Flashcards

1
Q

DELTA G,NEGATIVE.

A

IN ORDER FOR A REACTION TO BE FEASIBLE, THE GIBBS FREE ENERGY, DELTA G, MUST IN FACT BE NEGATIVE.

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2
Q

C-C BOND STRENGTH, COMPARED TO C=C BOND STRENGTH.

A

C-C BONDS CONTAINS ONE,1, SIGMA BOND.
C=C BOND, CONTAINS ONE,1, PI BOND AND ONE,1, SIGMA BOND.

SO A C=C BOND, IS WEAKER THAN TWO,2, C-C BONDS.
AS IT CONSISTS OF A PI AND A SIGMA BONDS, RATHER THAN TWO,2, SIGMA BONDS.

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3
Q

COMBUSTION, TYPE OF REACTION.

A

AN EXOTHERMIC REACTION, BONDS FORMED.
SO A NEGATIVE VALUE FOR THE ENTHALPY CHANGE OF COMBUSTION,
-KJmol^-1.

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4
Q

REASONS WHY A REACTION IS FEASIBLE, IN TERMS OF ENTROPY.

A

THE ENTROPY CHANGE OF THE SYSTEM IS ALWAYS POSITIVE.
BECAUSE THE ENTROPY OF THE SURROUNDINGS AND THE SYSTEM ARE BOTH ALWAYS POSITIVE.

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5
Q

ENTROPY CHANGE OF A SYSTEM, POSITIVE.
THE REASONS FOR THIS.

A

BECAUSE THERE IS AN INCREASED NUMBER OF MOLES.

A CHANGE OF STATE AS GAS, LIQIUD, SOLUTION, ARE PRODUCED FROM SOLID.

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