ENERGETIC, II. Flashcards
DELTA G,NEGATIVE.
IN ORDER FOR A REACTION TO BE FEASIBLE, THE GIBBS FREE ENERGY, DELTA G, MUST IN FACT BE NEGATIVE.
C-C BOND STRENGTH, COMPARED TO C=C BOND STRENGTH.
C-C BONDS CONTAINS ONE,1, SIGMA BOND.
C=C BOND, CONTAINS ONE,1, PI BOND AND ONE,1, SIGMA BOND.
SO A C=C BOND, IS WEAKER THAN TWO,2, C-C BONDS.
AS IT CONSISTS OF A PI AND A SIGMA BONDS, RATHER THAN TWO,2, SIGMA BONDS.
COMBUSTION, TYPE OF REACTION.
AN EXOTHERMIC REACTION, BONDS FORMED.
SO A NEGATIVE VALUE FOR THE ENTHALPY CHANGE OF COMBUSTION,
-KJmol^-1.
REASONS WHY A REACTION IS FEASIBLE, IN TERMS OF ENTROPY.
THE ENTROPY CHANGE OF THE SYSTEM IS ALWAYS POSITIVE.
BECAUSE THE ENTROPY OF THE SURROUNDINGS AND THE SYSTEM ARE BOTH ALWAYS POSITIVE.
ENTROPY CHANGE OF A SYSTEM, POSITIVE.
THE REASONS FOR THIS.
BECAUSE THERE IS AN INCREASED NUMBER OF MOLES.
A CHANGE OF STATE AS GAS, LIQIUD, SOLUTION, ARE PRODUCED FROM SOLID.