Emulsion 2 Flashcards

1
Q

how are emulsifications formed?

A

homogenising the two phases
-think about farm style milk

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2
Q

how does shear force affect particle size

A

reduces it

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3
Q

what is required to make an emulision

A

energy
emulsifier

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4
Q

what is laplace pressure

A

pressure difference between the inside and outside of a curved surface
-force holding the bubble out

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5
Q

how are droplets broken down into smaller droplets

A

applying energy greater than laplace energy

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6
Q

how is the energy provided

A

vigorous agitation

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7
Q

how are food oil-in-water emulsions usually produced?

A

colloid mills or high-pressure homogenizers

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8
Q

how many homogenisation categories are there and name them

A

2
primary
secondary

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9
Q

what is primary homogenisation

A

conversion of bulk liquid into emulsion
-quick whisk creates course emulsion

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10
Q

what is secondary homogenisation

A

reducing droplet size in existing emulsion
-add course emulsion to blender
-smaller more stable emulsion is produced

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11
Q

what is often used in the food industry to directly homogenise oil and aqueous phases

A

high speed mixers

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12
Q

what can be used to produce emulsions with fine droplets

A

high-pressure valve homogenisers

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13
Q

how does a high pressure valve homogeniser work

A

a coarse emulsion is pushed through a valve which creates pressure and shear turning it into a fine emulsion

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14
Q

describe how a microfluidiser works

A

under high pressure (6 atmos) two streams (1 aqueous, 1 oil) are brought together at the ‘impact zone’ which creates an emulsion
-can be used for secondary but it usually makes primary

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15
Q

factors that influence the efficacy of the creation of an emulsion

A

pressure
time between collisions
concentration of emulsifier
solubility of emulsifier
HLB number
propensity for adsorption of emulsifier to surface

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16
Q

other factors effecting emulsification efficiacy

A

time for migration of the emulsifier to interface
flexibility fo the emulsifier on the surface after adsorbtion
solution conditions such as pH and ionic strength
temperature
fat or oil content

17
Q

why is time important

A

rapid adsorbtion results in less coaslecnece, finer droplets and better emulsification

18
Q

types of physcial instability

A

creaming
sedimentation
coalscence
flocculation
ostwald
ripening
breaking (phase seperation)

19
Q

what is creaming

A

emulsion particles rise due to lower density

20
Q

what is sedimentation

A

particles settle at bottom due to higher density

21
Q

what is coalscence

A

particles merge to form larger particles
average droplet size increases over time

22
Q

what is flocculation

A

particles aggregate without coalensnce due to attractive forces

23
Q

what is ostwald ripening

A

growth of larger particles at the expense of smaller ones

24
Q

what is breaking

A

complete seperation of phases

25
Q

what is stokes law

A

used to describe the velocity of seperation

26
Q

what is the driving force of seperation

A

gravity

27
Q

stokes law equation, write it down

A

V= 2gr^2 (p2-p1)/9n

28
Q

what is r

A

radius of particle

29
Q

what is p2

A

density of continous phase

30
Q

what is p1

A

density of dispersed phase

31
Q

what is n

A

viscosity of continuous phase

32
Q

what is the driving force for emulsion coalscence

A

thinning and disruption of the liquid film

33
Q

how can coalescence be avoided?

A

having a stable interfacial layer

34
Q
A