Eletrolysis Flashcards

1
Q

What is electrolysis?

A

The decomposition of a compound using electricity.

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2
Q

What is the electrolyte in electrolysis?

A

The compound (molten or aqueous) that is being decomposed by the electricity.

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3
Q

What is the positive electrode called in electrolysis?

A

Anode.

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4
Q

What type of ions are attracted to the anode?

A

Anions / negative ions.

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5
Q

What occurs at the positive electrode during electrolysis?

A

Negatively charged ions lose electrons - oxidation.

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6
Q

What is the negative electrode called in electrolysis?

A

Cathode.

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7
Q

What type of ions are attracted to the cathode?

A

Cations / positive ions.

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8
Q

What occurs at the negative electrode during electrolysis?

A

Positively charged ions gain electrons - reduction.

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9
Q

What happens to solid ionic compounds during electrolysis?

A

The ions are in a fixed lattice and are not free to move.

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10
Q

What is the state of ionic compounds that allows them to conduct electricity?

A

Molten or aqueous.

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11
Q

What do molten ionic liquids split into during electrolysis?

A

Their elements.

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12
Q

What is produced at the cathode during electrolysis?

A

Metals.

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13
Q

What is produced at the anode during electrolysis?

A

Non-metals.

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14
Q

What makes the electrolysis of aqueous ionic compounds more complicated?

A

The presence of more ions, including H+ and OH- ions.

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15
Q

At the cathode, what determines whether a metal ion or hydrogen forms?

A

The reactivity of the metal compared to hydrogen.

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16
Q

If the metal is less reactive than hydrogen, what will form at the cathode?

A

The metal.

17
Q

At the anode, what competes for discharge against non-metals?

A

OH- ions.

18
Q

If the non-metal is a halide (F, Cl, Br, I), what will always be discharged at the anode?

A

The halogen.

19
Q

What is an example of a halogen forming during electrolysis?

A

Chloride becoming chlorine (Cl2).

20
Q

What occurs if the non-metal is not a halide during electrolysis?

A

OH- will discharge into O2 + H2O.

21
Q

What is one way to set up an electrolysis experiment to obtain gas?

A

Using inverted test tubes or a gas syringe.

22
Q

What is the test for chlorine gas?

A

It bleaches damp litmus paper, turning it white.

23
Q

What sound does hydrogen make when burned with a lighted splint?

A

A squeaky pop.

24
Q

What happens to a glowing splint in the presence of oxygen?

A

It relights.

25
Q

What is the primary ore of aluminium?

A

Bauxite (Al2O3).

26
Q

How are metals extracted from their ores using electrolysis?

A

By melting the ore and producing the required current.

27
Q

Why is electrolysis used for extracting certain metals?

A

When the metal is too reactive to be extracted by reduction with carbon or if the metal reacts with carbon.

28
Q

What is the role of cryolite in the extraction of aluminium?

A

It lowers the operating temperature by allowing the mixture to move freely at a lower temperature.

29
Q

What do the positive Al³⁺ ions do during electrolysis?

A

They are attracted to the negative electrode, pick up three electrons each, and turn into neutral aluminium.

30
Q

What do the negative O²⁻ ions do during electrolysis?

A

They are attracted to the positive electrode, lose two electrons, and form neutral oxygen atoms.

31
Q

What is a consequence of using carbon electrodes in electrolysis?

A

The anodes need to be replaced often as they react with oxygen to form carbon dioxide.

32
Q

What do half equations show?

A

The reactions that happen at the electrodes.

33
Q

Fill in the blank: For the electrolysis of aqueous sodium chloride, the half equation for hydrogen is _______.

A

2H⁺ + 2e⁻ → H₂

34
Q

What is the ionic equation for the electrolysis of aqueous sodium chloride?

A

2H⁺ + 2Cl⁻ → H₂ + Cl₂

35
Q

What is a method to obtain copper from copper sulfate?

A

By displacement with scrap iron or by electrolysis.

36
Q

What are the two processes mentioned for obtaining copper from ores?

A
  • Bioleaching
  • Phytomining