Electrolysis Flashcards

1
Q

What does an electrolytic cell consist of

A
  • Battery
  • Electrodes
  • Electrolyte
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2
Q

Which is the positive electrode

A

Anode

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3
Q

What are some weak electrolytes

A
  • Weak acids and alkalis
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4
Q

Which is the negative electrode

A

Cathode

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5
Q

Define electrolysis

A

Electrolysis is the chemical decomposition of a compound by passing electricity through the compound when molten or aqueous

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6
Q

Define an electrolyte

A

An electrolyte is a compound which when molten or aqueous, conducts electricity with its decomposition at the electrodes

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7
Q

What reaction takes place at the cathode

A

Reduction

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8
Q

What are some strong electrolytes

A
  • Strong acids and alkalis
  • Salt solutions
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9
Q

What reaction takes place at the anode

A

Oxidation

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10
Q

Define a binary compound

A

A binary compound is a compound containing only 2 elements

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11
Q

Why are there OH- and H+ ions in aqueous solutions

A

Water undergoes reversible self-ionisation to produce a small concentration of OH- and H+ ions

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12
Q

What are the factors affecting the discharge of ions during electrolysis

A
  • Relative position of ions in electrochemical series
  • Relative concentration of ions
  • Nature of electrode
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13
Q

Why will the ion that is lower in the electrochemical series be preferentially discharged

A
  • Ion is less stable
  • Ion gains electrons more easily to be discharged as a metal
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14
Q

Which anions are usually not discharged

A
  • F-
  • SO42-
  • NO3-
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15
Q

Define electroplating

A

Electroplating is the coating of the surface of an object with a thin layer of a metal by electrolysis

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16
Q

What is the equation for discharge of hydroxide ions

A

4OH-
–> 2H2O + O2 + 4e-

17
Q

In electrolysis, where is the object to be coated placed

A

Cathode

18
Q

What impurities are found in impure copper

A

Silver and gold

19
Q

How can the thickness of electroplating be adjusted

A

Adjusting:
- Magnitude of current
- Time duration of process

20
Q

What is a simple cell

A

A simple cell is a device that converts chemical energy to electrical energy

21
Q

Which is the negative electrode in a simple cell

A

More reactive metal

22
Q

How do electrons flow in a simple cell

A

From more reactive metal to less reactive metal

23
Q

Which is the positive electrode in a simple cell

A

Less reactive metal

24
Q

Where does reduction occur in a simple cell

A

Positive electrode

25
Q

How to increase voltage produced in a simple cell

A

Use metals for the electrodes that are far apart in the reactivity series

26
Q

When will the voltmeter read 0V in a simple cell

A

When electrodes are made of the same metal

27
Q

Define a fuel cell

A

A fuel cell is a chemical cell in which reactants are continuously supplied to produce electricity directly

28
Q

Where is the negative electrode in a fuel cell

A

Side where fuel enters

29
Q

Where is positive electrode in fuel cell

A

Side where oxygen enters

30
Q

How do electrons flow in a fuel cell

A

From negative to positive electrode