Electrolysis Flashcards
What does an electrolytic cell consist of
- Battery
- Electrodes
- Electrolyte
Which is the positive electrode
Anode
What are some weak electrolytes
- Weak acids and alkalis
Which is the negative electrode
Cathode
Define electrolysis
Electrolysis is the chemical decomposition of a compound by passing electricity through the compound when molten or aqueous
Define an electrolyte
An electrolyte is a compound which when molten or aqueous, conducts electricity with its decomposition at the electrodes
What reaction takes place at the cathode
Reduction
What are some strong electrolytes
- Strong acids and alkalis
- Salt solutions
What reaction takes place at the anode
Oxidation
Define a binary compound
A binary compound is a compound containing only 2 elements
Why are there OH- and H+ ions in aqueous solutions
Water undergoes reversible self-ionisation to produce a small concentration of OH- and H+ ions
What are the factors affecting the discharge of ions during electrolysis
- Relative position of ions in electrochemical series
- Relative concentration of ions
- Nature of electrode
Why will the ion that is lower in the electrochemical series be preferentially discharged
- Ion is less stable
- Ion gains electrons more easily to be discharged as a metal
Which anions are usually not discharged
- F-
- SO42-
- NO3-
Define electroplating
Electroplating is the coating of the surface of an object with a thin layer of a metal by electrolysis